The present invention relates to a method of manufacturing enamels selected from: polyurethanes, polyamides, 
polyamide-imides, polyesters, 
polyester-imides, 
polyester amide-imides, polyimides, polyepoxy compounds, and polyphenyl 
oxide compounds; said method comprising an operation in which a functionalized polysiloxane 
oligomer is obtained by causing a functionalized polysiloxane having a reactive first functional group to react with a first functionalized 
monomer used in synthesizing said enamel, said first 
monomer having a second functionalized group that reacts with said first functional group. According to the invention, the method subsequently comprises the following operations: said functionalized polysiloxane 
oligomer is caused to react with a second functionalized 
monomer that is used in synthesizing said enamel, said second monomer having a third functional group that reacts with said functionalized polysiloxane 
oligomer, thereby obtaining a grafted polysiloxane having organic chains that are identical to those of said enamel; and said enamel is synthesized using said first and second monomers and said grafted polysiloxane.