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30results about How to "Inhibit surface activity" patented technology

Electrolyte additive, high-voltage electrolyte and lithium ion battery containing electrolyte additive

The invention discloses an electrolyte additive, a high-voltage electrolyte and a lithium ion battery containing the electrolyte additive. The high-voltage electrolyte is prepared by adding the electrolyte additive into the conventional electrolyte; the conventional electrolyte comprises a non-aqueous organic solvent and lithium salt, wherein the content of the non-aqueous organic solvent is 80-85 percent of the total mass; the mass of the electrolyte additive is 0.01-10 percent of the total mass; and the electrolyte additive is maleic anhydride C4H2O3 or one of derivatives thereof and has the structure formula as shown in the abstract. According to the high-voltage electrolyte, a stable interfacial film can be formed on the surfaces of a positive electrode and a negative electrode, the reaction activity on the electrode surface is inhibited, oxidative decomposition of the electrolyte is reduced, and gas swelling is effectively inhibited, so that the safety performance and the cycle performance of the lithium ion battery under normal pressure and high voltage are improved and the service life of the lithium ion battery under normal pressure and high voltage is prolonged. The electrolyte is simple in preparation process and is suitable for industrial production.
Owner:JIANGXI YOULI NEW MATERIALS

High-voltage electrolyte and lithium ion battery containing electrolyte

InactiveCN105762412AElectrochemical and chemical stabilityInhibit surface activitySecondary cellsElectrolytesDouble bondLithium electrode
The invention belongs to the technical field of lithium ion battery materials, and discloses high-voltage electrolyte and a lithium ion battery containing the electrolyte. The high-voltage electrolyte is obtained by adding a functional additive to common electrolyte, wherein the mass of the functional additive is equivalent to 0.1-5% of that of common electrolyte, and the functional additive refers to an alkene dinitrile type compound. According to the high-voltage electrolyte and the lithium ion battery containing the electrolyte disclosed by the invention, the alkene dinitrile type compound containing nitrogen elements and double-bond functional groups is used as a high-voltage film forming additive of the lithium ion electrolyte, the additive is based on the oxidation or the reduction of double bonds, and a layer of compact passivating films can be formed on the surface of a positive pole and the surface of a negative pole in the process of first charge and discharge. Stable cyanogen bases are introduced, so that surface films are stabler in electrochemistry and chemistry. The cycle performance of the lithium ion battery containing the additive of the electrolyte under 3-4.5V is improved, the safety performance and the energy density of the lithium ion battery are improved, and the service life of the lithium ion battery is prolonged.
Owner:SOUTH CHINA NORMAL UNIVERSITY

Method for preparing non-aqueous electrolyte suitable for high-energy density lithium ion batteries

The invention discloses a method for preparing non-aqueous electrolyte suitable for high-energy density lithium ion batteries and relates to the technical field of electrochemistry. The preparation method comprises the following steps: (a) carrying out reduced pressure distillation, purification and lithiated molecular sieve dehydration on a 80-85wt% of organic solvent in the presence of nitrogen to obtain a refined non-aqueous organic solvent, wherein the purity of the non-aqueous organic solvent is greater than 99.99 and the water content is less than 10ppm; (b) adding 12-15wt% of lithium salt in the purified solvent to make the concentration be 1M and obtain basic electrolyte; (c) adding a 0.01-3wt% of additive A and a 0.1-6wt% of additive B into the electrolyte. The method has the advantages that thiophene, benzothiophene, 2-thiophene formonitrile and 2-methylthiophene are adopted as electrolyte additives, the electrolyte can be electrolyzed on the surface of an electrode to form a compact protective film, surface films of positive and negative electrodes are optimized and the surface activity of the electrodes is inhibited, so that the oxygenolysis of the electrolyte main solvent at high voltage is inhibited, the high voltage cycle performance of the lithium ion batteries is improved and the gas expansion phenomenon is reduced.
Owner:JIANGXI YOULI NEW MATERIALS

Trimethyl borate additive contained high-voltage functional electrolyte and preparation method and application therefor

The invention discloses a trimethyl borate additive contained high-voltage functional electrolyte and a preparation method and an application therefor. The electrolyte is obtained by adding a functional additive to a common electrolyte; the common electrolyte is formed by a cyclic carbonate solvent, a linear carbonate solvent and a conductive lithium salt; and the functional additive adopts trimethyl borate. According to the functional electrolyte, the trimethyl borate additive is taken as the high-voltage film-forming additive for the lithium ion electrolyte; the additive is relatively low in oxidization and reduction potential, so that a compact and stable SEI film layer can be formed on the surfaces of a positive electrode and a negative electrode in the first charge-discharge process; therefore, the films on the surfaces of the positive electrode and the negative electrode are optimized, the resistance between the positive electrode and the electrolyte is lowered, and the surface activity of the electrodes is restrained, so that the further contact between the electrolyte and the electrode active material is restrained consequently, and the oxidization and decomposition of the electrolyte main body solvent on the electrode surface is lowered; and the cycling performance and the rate capability of the electrolyte additive contained lithium ion battery under 3-4.5V can be improved.
Owner:SOUTH CHINA NORMAL UNIVERSITY

High-voltage electrolyte with rapid charge function and preparation method and application thereof

The invention discloses a high-voltage electrolyte with a rapid charge function and a preparation method and application thereof, and belongs to the technical field of a lithium ion battery. The electrolyte is prepared by adding a functional additive in an amount equivalent to 1-5% of the mass of a conventional electrolyte into the conventional electrolyte, wherein the functional additive is difluoromethyl phenyl sulfone. The functional additive difluoromethyl phenyl sulfone can be used as a high-voltage and rapid-charge film formation additive; since the additive has relatively low oxidization potential, a compact and stable interface film can be formed on a surface of a positive electrode during the initial charge-discharge process, the surface membrane of the positive electrode is optimized, the surface activity of an electrode is prevented, so that further contact of the electrolyte and an electrode active substance and HF formation are prevented, and oxidization and decomposition of an electrolyte main solvent in the surface of the electrode are reduced; and the room-temperature cycle property and the rate performance of the lithium ion battery containing the functional additive are improved under 3-4.35V, and the lithium ion battery has favorable application prospect.
Owner:SOUTH CHINA NORMAL UNIVERSITY

Bulk concentrate flotation separation method based on reinforcement of lead sulfide inhibition

InactiveCN109225654AThe effect is highly targetedThe function and effect are thoroughFlotationAmmonium sulfateOre concentrate
The invention discloses a bulk concentrate flotation separation method based on reinforcement of lead sulfide inhibition. Firstly, wet process pretreatment is conducted on the bulk concentrate, the inhibition to lead sulfide in the bulk concentrate is selectively reinforced, then sulfuric acid or a mixture of the sulfuric acid and manganese dioxide and a mixture of sulfuric acid and ammonium persulfate is added, filtration is performed after heating and stirring, filtrate can be recycled, a filter cake is washed till pH is close to the neutral, then water is added for size mixing, then terpenic oil is used as a foaming agent, and the flotation separation is performed by adopting the flotation process of rough flotation, fine flotation and re-flotation of middlings. The method based on theprocess of separating lead and other ingredients in vulcanized bulk concentrate has the advantages that the steps complement each other's advantages, agent preparation is simple, copper-lead or lead-zinc separation is thorough, the cost is low and the recovery rate is high, is applied to copper-lead, lead-zinc or copper-lead-zinc bulk concentrates, achieves economic and efficient copper-lead and lead-zinc separation of copper-lead or lead-zinc vulcanized bulk concentrates, remarkably improves the utilization rate of copper, lead and zinc resources and is good in effect.
Owner:KUNMING UNIV OF SCI & TECH +1

A Flotation Separation Method of Mixed Concentrate Based on Enhanced Suppression of Lead Sulfide

InactiveCN109225654BThe effect is highly targetedThe function and effect are thoroughFlotationEngineeringManganese oxide
The invention discloses a bulk concentrate flotation separation method based on reinforcement of lead sulfide inhibition. Firstly, wet process pretreatment is conducted on the bulk concentrate, the inhibition to lead sulfide in the bulk concentrate is selectively reinforced, then sulfuric acid or a mixture of the sulfuric acid and manganese dioxide and a mixture of sulfuric acid and ammonium persulfate is added, filtration is performed after heating and stirring, filtrate can be recycled, a filter cake is washed till pH is close to the neutral, then water is added for size mixing, then terpenic oil is used as a foaming agent, and the flotation separation is performed by adopting the flotation process of rough flotation, fine flotation and re-flotation of middlings. The method based on theprocess of separating lead and other ingredients in vulcanized bulk concentrate has the advantages that the steps complement each other's advantages, agent preparation is simple, copper-lead or lead-zinc separation is thorough, the cost is low and the recovery rate is high, is applied to copper-lead, lead-zinc or copper-lead-zinc bulk concentrates, achieves economic and efficient copper-lead and lead-zinc separation of copper-lead or lead-zinc vulcanized bulk concentrates, remarkably improves the utilization rate of copper, lead and zinc resources and is good in effect.
Owner:KUNMING UNIV OF SCI & TECH +1
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