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90 results about "Permanganate index" patented technology

The permanganate index is an assessment of water quality. It involves the detection of oxidation by potassium permanganate in an acid medium under hot conditions. The method is to heat a sample in a boiling water-bath with a known amount of potassium permanganate and sulphuric acid for a fixed period time (10 min). Part of the permanganate will be reduced by oxidizable material in the sample. The consumed permanganate can be determined by addition of an excess of oxalate solution, followed by titration with permanganate. The method applies to waters having a chloride ion concentration of less than 300 mg/L. Samples having a permanganate index over 10 mg/L should be diluted before analysis. The lower limit of the optimum range of the test is 0.5 mg/L.

Method for predicting chlorophyll a concentration in water based on BP nerval net

The invention relates to a density forecast method of the chlorophyll a stemmed from a water body of the BP neural network. The density forecast method comprises the following steps: (1) the chlorophyll a in the tested water body and the value of other correlative water quality index which influences the chlorophyll a are acquired as the examination data. (2) The neural network of an error back propagation is established. (3) The neural network is trained and tested. (4) The neural network which passes the test is utilized to forecast the chlorophyll a in the water body. Other water qualities which influence the chlorophyll a are: Ammonia nitrogen, total nitrogen, total phosphorus, orthophosphate, permanganate index, temperature, dissolved oxygen, pH, suspension, five-day biochemical oxygen demand. The step (1) also comprises a normalization process. The data of the chlorophyll a and other ten water quality indexes are between -1 and +1 after the data of the chlorophyll a and other ten water quality indexes are normalized. The neural network comprises an input layer, an intermediate layer and an output layer. The invention can establish a forecast model related to the chlorophyll a, just needing the experiment which has the limited times. The chlorophyll in the river can be accurately and quickly forecasted through the computer simulation experiment and the science forecast.
Owner:TIANJIN MUNICIPAL ENG DESIGN & RES INST

High pressure flow injection rapid analysis system for permanganate index of water quality

The invention relates to a high pressure flow injection rapid analyzing system of water permanganate index. A pollution system comprises a heater, a cooler, a photoelectric circulation pool, a sulfuric acid storing bottle, a potassium permanganate storing bottle, a constant flow injection pump, a peristaltic pump, two sampling six-way conversion valves and a flow loading tee conversion valve which are connected into a system through capillary pipes. The sapling valve is provided with a sample quantitative ring and a potassium permanganate quantitative ring. The output end of the photoelectric circulation pool is connected with a capillary dorsal press pipe. Flow channels are switched through the conversion valves by the system. Quantitative water sample and potassium permanganate reagent are respectively switched into the continuously flowing loading solution. The processes of mixing, heating, reacting, cooling, photoelectric detecting, and the like of a sample with the reagent are finished in the continuously flowing process. The detection result is obtained. Instant analyzing data are obtained conveniently and rapidly. The system is applied to the timing or random online monitoring of the permanganate index of source water of rivers and water factories or industrial emission water, etc.
Owner:DELIN ENVIRONMENTAL PROTECTION TECH

Method for quickly detecting hypermanganate index in water by molecular absorption spectrometry

The invention discloses a method for quickly detecting hypermanganate index in water by molecular absorption spectrometry. The method comprises the following steps: selecting a color comparison tube to extract a water sample, adding proper sulfuric acid to ensure the water sample is of acidity; adding 0.01 to 0.2umol/L of hypermanganate solution, and heating for 30 minutes in a heat reactor at 100 DEG C; cooling, reducing the residual hypermanganate with nitrite, and adding excessive nitrite to react 3 to 5 minutes; putting 1ml of the reaction solution after constant volume in a 25ml color comparison tube; adding citric acid-ethanol solution, and converting the nitrite into nitrogen dioxide instantly; and carrying gas-phase molecules to an absorption tube by carrier gas, and detecting the light absorption value at the position of 213.9 nano-wavelength. The invention establishes a quick quantitative analysis method for the hypermanganate index in the water by an indirect nitrite detection mode, has the characteristics of quick detection, high accuracy, less turbidity influence, little reagent and safety and environmental protection, and can be widely applied to emergency, online detection, flowing injection, lab information management and the like.
Owner:浙江中通检测科技有限公司

Permanganate index on-line monitoring automatic titration determination method and device

The invention discloses a permanganate index on-line monitoring automatic titration determination method and device; based on an automatic measurement flow, an end point is jointly determined with cooperation of two ways of absorbance and electric potentials, and the relationships of the changes of the solution absorbance and the electric potentials with the titration volume are simultaneously used in the titration determination method, staging and selective design is performed for the entire titration process, and different titration speeds are adopted in different titration stages so as to ensure the accuracy of the titration. Two conditions of the absorbance and the electric potentials are used at the same time; when the solution not only meets conditions of photometric determination ofthe end point but also meets the conditions of electrode determination of the end point during automatic titration, the titration is determined to reach the end point; through a specific titration algorithm and the determination way, the method and device solve the problems that the electric potential generates aging and drifting because a traditional photometric method is interfered by water colors, turbidity and other factors and an ORP electrode is used for a long time.
Owner:ZHONGXING INSTR SHENZHEN

Method for rapidly measuring permanganate indexes in water by spectrophotometric method

The invention relates to a method for rapidly measuring permanganate indexes in water by a spectrophotometric method. The method comprises the following steps: selecting a colorimeter tube and extracting a water sample; adding a proper amount of sulfuric acid until the water sample is acidic; adding 0.01mu mol/L-0.2mu mol/L of permanganate solution and heating the obtained mixed solution in a heating reactor at 100 DEG C for 15-45 minutes; after the mixed solution is cooled, reducing the remaining permanganate with excessive nitrite, and then adjusting the obtained reaction solution into a constant volume after the reaction; taking out and placing 1ml of the reaction solution with a constant volume in the colorimeter tube of 25ml, adjusting the reaction solution into a constant volume once again, and sequentially adding 0.5ml of sulfanilamide and 0.5ml of ethylenediamine; and standing for 10 minutes, and taking water as a reference and measuring the absorbancy by a cuvette with the optical path length of 10mm at the position with the wavelength of 10mm. In the invention, a rapid quantitative analysis method of the permanganate indexes in the water is established by the mode of indirectly measuring the nitrite; the method is rapid and economical, and the process of titrating sodium oxalate with the permanganate can be avoided; and the method can be widely applied to emergency, online monitoring, flow injection, lab informatization management and the like.
Owner:宁波市环境监测中心

Coupling water supply purifying method of biological reinforced powder active carbon and diatomite

The present invention relates to a coupling water supply purifying method of biological reinforced powder active carbon and diatomite, which comprises the following steps: firstly, powder active carbon and diatomite are continuously fed into raw water which needs to be purified quantitatively to be stirred to mix through mechanism to enable the powder active carbon and the diatomite to suspend in water to absorb organic matters in the raw water; then, biological powder active carbon and diatomite particles coated with microorganism are formed by a labor reinforced method; and organic pollutants in the raw water is further degraded by a microorganism function. Compared with the prior art, on the basis of the coupling water supply purifying technique of biological reinforced powder active carbon and diatomite, the present invention has three functions of absorption, biological degradation and dynamic film separation, and can further reduce the content of pollutants in the raw water, in particular to aim to the problems of high raw-water permanganate index, ammonian and organic pollutants, and the like. Thus, drinking water after being purified satisfies every index in the new sanitary standard for life drinking water GB 5749-2006 issued by China.
Owner:华方水务(中国)有限公司

Acid and alkali permanganate index on-line one-machine monitoring system and detection method thereof

The invention provides an acid and alkali permanganate index on-line one-machine monitoring system and the detection method thereof. The acid and alkali permanganate index on-line one-machine monitoring system includes an ARM9 main-control system, a permanganate index on-line monitoring instrument and a chloride ion concentration measuring instrument, wherein the ARM9 main-control system is connected with the permanganate index on-line monitoring instrument and the chloride ion concentration measuring instrument through a CAN bus respectively; the permanganate index on-line monitoring instrument includes a peristaltic pump, a measuring cup, a liquid level detector, a ten-port multi-position valve, a digestion titration device, a water sample, a reagent and distilled water; the water sample, the reagent and the distilled water are connected with distribution ports of the ten-port multi-position valve respectively; the lower end of the measuring cup is connected with a common port of the ten-port multi-position valve; the peristaltic pump is connected with the upper end of the measuring cup through a pipeline; the liquid level detector is installed at the upper part of the measuring cup; and one distribution port of the ten-port multi-position valve respectively is connected with a liquid inlet / outlet of the digestion titration device. Considering the economy and environmental protection, the invention provides a technical device for measuring the permanganate index through integrating the two standard acid and alkali permanganate index methods.
Owner:YIWEN ENVIRONMENTAL SCI & TECH GUANGZHOU

Measurement method for permanganate index and application

The invention discloses a measurement method for a permanganate index. The method comprises the following steps: (1) adding a to-be-measured water sample into a colorimetric tube provided with a plug, adding (1+10) sulfuric acid for acidification, adding a potassium permanganate solution, and shaking uniformly; (2) digesting the water sample in the step (1) under a certain condition and quickly cooling to a room temperature; (3) adding an excessive ammonium ferrous sulfate solution into a digestion solution in the step (2), and shaking uniformly; (4) adding a proper amount of a sulfosalicylic acid aqueous solution into a reaction solution in the step (3) for producing a color development reaction; (5) performing absorbance testing on the water sample in the step (4) by taking de-ionized water as a reference at the wavelength of 510 nm, and calculating the permanganate index of the water sample by a formula IMn=-8.5*(A-A0), wherein in the formula, IMn is the permanganate index of the water sample, A is the absorbance of the water sample, and A0 is the absorbance of a blank solution. The measurement method is quick and accurate in detection, suitable for batch measurement and simple to operate, and can be widely applied to laboratory detection and outdoor emergency detection.
Owner:北京连华永兴科技发展有限公司

Multi-parameter water quality detection method and multi-parameter water quality detector based on same

A multi-parameter water quality detection method comprises the steps as follows: (1) preparing a standard solution, (2) creating a standard curve, 3) sampling a sample, 4) preprocessing the sample, 5) performing experimental determination and 6) calculating permanganate index concentration, ammonia nitrogen concentration and total nitrogen concentration. A multi-parameter water quality detector comprises a main unit body provided with a storage bin and an experiment bin. According to the detection method, detection of a permanganate index, ammonia nitrogen, total nitrogen, nitrite nitrogen and nitrate nitrogen of a to-be-detected substance is realized through an absorption spectrum, the operation procedure is simplified, the on-line condition of the detector is facilitated, the defects of many required instruments and high cost of the different traditional methods are overcome, multiple parameters can be detected on line in real time by one detector, the measurement time is short, the accuracy is high, the detection limit is low, the lowest detection limit of total nitrogen is 0.5 mg/L, the lowest detection limit of ammonia nitrogen is 0.1 mg/L, the lowest detection limit of the permanganate index is 0.1 mg/L, and the detection requirements of the Quality standard for ground water and the Environmental quality standards for surface water (GB3838-2002) for total nitrogen, ammonia nitrogen and the permanganate index can be met.
Owner:QINGDAO JIAMING MEASUREMENT & CONTROL TECH

Water quality on-line permanganate index monitor and detecting method

The invention relates to a water quality on-line permanganate index monitor, comprising a chassis, wherein a touch display is mounted on the chassis; an industrial control machine, a digestion unit, atitration unit, a sampling unit, a liquid adding unit and a drainage storage unit are mounted in the chassis; the digestion unit, the titration unit, the sampling unit, the liquid adding unit and thedrainage storage unit are respectively connected to the industrial control machine; a sulfuric acid quantification bottle, a sodium oxalate quantification bottle, a pure water quantification bottle and a water sample quantification bottle are all mounted with capacitive sensors. The monitor can achieve independent injection and drainage, and a semi-closed digestion pool can perform high temperature digestion of a sample to resolve metal ions; the solution can be mixed thoroughly by means of a stirring motor, and electrodes can be well cleaned. The invention also relates to a detecting methodof the water quality on-line permanganate index monitor, which can achieve continuous monitoring of an on-line water quality permanganate index to reflect the change of the water quality permanganateindex at any time, thereby reducing the workload of monitoring personnel.
Owner:SHANGHAI YIDIAN SCI INSTR

Syringe pump sample injection gas phase molecule absorption spectrometer

The invention discloses a syringe pump sample injection gas phase molecule absorption spectrometer, and relate to the technical field of optical analysis. The spectrometer is aimed at problems that an existing sample injection device needs frequent replacement of a peristaltic pump pipe, has low precision, can not realize function of automatic dilution in any ratio, and can only determine one substance to be measured at one time, with low work efficiency. The spectrometer provided by the invention comprises a sample injection device, a gas-liquid separation device, a drying device, a heating device and a detection device. The sample injection device comprises at least one sample injection pipes; and an output end of the sample injection pipe is connected with the gas-liquid separation device and for sending a reagent to the gas-liquid separation device; the sample injection pipe comprises a syringe pump, a sample injection duct communicating with the syringe pump, and at least one sample injection branch pipe respectively communicating with the sample injection duct and for sending different reagents to the sample injection duct successively. The invention is particularly suitable for determination of indexes of ammonia, sulfide, Kjeldahl nitrogen, total nitrogen, nitrate, nitrite, sulfite, chloride ion, and potassium permanganate.
Owner:上海北裕分析仪器股份有限公司

Method for measuring permanganate index with phenanthroline-ferrous ion color development method and application

The invention discloses a method for measuring a permanganate index with a phenanthroline-ferrous ion color development method. The method comprises the following steps: (1) adding a to-be-measured water sample into a colorimetric tube provided with a plug, adding (1+7) sulfuric acid for acidification, adding a potassium permanganate solution, and shaking uniformly; (2) digesting the water sample in the step (1) under a certain condition and quickly cooling to a room temperature; (3) adding an ammonium ferrous sulfate solution into a digestion solution in the step (2), and shaking uniformly; (4) adding a phenanthroline-sodium acetate aqueous solution into a reaction solution in the step (3) for adjusting the pH (potential of hydrogen) value of a system to be 3-5, and producing a color development reaction; (5) performing absorbance testing on the water sample in the step (4) by zero setting of a reference solution at the wavelength of 510 nm, and calculating the permanganate index of the water sample by a formula IMn=7.666A-0.012, wherein in the formula, IMn is the permanganate index of the water sample and A is the absorbance of the water sample. The measurement method is high in color development reaction selectivity, strong in anti-jamming capability, complete in reaction and simple and convenient to operate.
Owner:北京连华永兴科技发展有限公司

Full-automatic permanganate index analyzing system

The invention discloses a full-automatic permanganate index analyzing system. The system is provided with a controller and comprises an automatic sampling device and an automatic slaking device, wherein the automatic sampling device comprises a base I, a second rotating disc is arranged on the base I, a sample bottle is arranged on the second rotating disc, a third linear motion module is arrangedabove the second rotating disc, and a cleaning pipe and a sampling pipe are arranged on the third linear motion module; and the automatic slaking device comprises a base II, a first rotating disc, aheating titration region and reagent bottles are sequentially arranged along the length direction of the base II, a reaction bottle is arranged on the first rotating disc, a second linear motion module is arranged above the first rotating disc, a sample feeding pipe and a pure water pipe are arranged on the second linear motion module, the sample feeding pipe is connected with the sampling pipe through a peristaltic pump, a titration rod is arranged above the heating titration region, the reagent bottles are respectively connected with the pure water pipe and the titration pipe, a first linearmotion module is arranged on the base II, and an electric gripper is arranged on the first linear motion module.
Owner:JINAN SENTE ELECTRONICS TECH

Method for online automatic detection of permanganate index in water

The invention discloses a method for online automatic detection of permanganate index in water. The method comprises the following steps: preparing a used reagent; finishing calibration of a standardcurve, and verifying the accuracy and repeatability of online automatic detection equipment and glucose test; manually testing different types of surface water and standard solutions thereof in a laboratory according to a national standard method to obtain permanganate indexes in the surface water; testing the corresponding surface water and the standard solution thereof by online automatic detection equipment to obtain absorbance; enabling the online automatic detection equipment to calculate permanganate indexes in different types of surface water according to the standard curve; and comparing a laboratory method with an automatic calculation method, calculating a relative error, and judging whether the relative error is within a standard requirement range. By using the method provided by the invention, the accuracy and repeatability of the online automatic detection equipment are good, the glucose test and the adding standard recovery rate meet the requirements, and the method has great significance for environmental protection in the field of online monitoring of surface water quality.
Owner:左航

Multifunctional multi-channel sample loading device for permanganate index analyzer

The invention relates to a multifunctional multi-channel sample loading device for a permanganate index analyzer. The multifunctional multi-channel sample loading device for the permanganate index analyzer comprises a shell, four groups of sample loading units, a four-way reversing valve, and a mobile sample loading head, wherein the sample loading units aremounted in the shell and used for independently adding reagents required for a test, and each group of sample loading unitscomprises a syringe pump; a pure water sample injection port, a reagent sample injection port, a sample discharging port, and a syringe pump connection port are formed in the four-way reversing valve correspondingly,and the four-way reversing valve isconnected with the syringe pump through the syringe pump connection port; and the mobile sample loading head is movably arranged in the shell and horizontally moves in the shell, and the mobile sample loading head is connected with the sample discharging port of thefour-way reversing valve. Compared with the prior art, the multifunctional multi-channel sample loading device for the permanganate index analyzer adopts a 4-channel sample injection system design, cross-contamination between different reagents is effectively avoided, and reliability of experimental result data is improved; no pipeline is reused, the cumbersome reused pipeline cleaning and liquidthrowing processesare reduced, liquid addition efficiency is improved, and analysis and measurement time are saved.
Owner:SHANGHAI ANJIE ENVIRONMENTAL PROTECTION TECH

Method of electrochemically measuring permanganate index by virtue of stannic oxide nanometer electrode

The invention belongs to the technical field of environmental monitoring and relates to a method of measuring a permanganate index of a cleaner water body by utilizing an electrochemical method, wherein the method is characterized in that a stannic oxide nanometer electrode which utilizes metal titanium as a substrate and has a surface in a nanometer stick array structure is utilized as working electrode, the stannic oxide nanometer electrode is prepared by utilizing a hydrothemal method to cause SnCl4.5 H2O and NaOH which are utilized as precursors to react on the metal titanium substrate at180-200 DEG C for 16-24 hours; a working voltage when in electrochemical measurement is respectively 1.7-2.2 V when a saturated silver/chlorinated silver electrode is utilized as a reference electrode and 1.65-2.15 V when a saturated calomel electrode is utilized as a reference electrode, the concentration of sodium sulfate or sodium nitrate in the electrolyte solution is 0.08-0.4 mol/L. According to the invention, no toxic materials can be generated when in measurement, and the method provided by the invention has the advantages of high measurement accuracy, low detection limit, permanganateindex detection lower limit up to 0.2 mg/L (S/N=3), simplicity and convenience in operation and short single measurement time less than 5 minutes.
Owner:DALIAN UNIV OF TECH

Method for testing permanganate index though gas phase molecular absorption spectroscopy

The invention discloses a method for testing a permanganate index though gas phase molecular absorption spectroscopy. The method comprises the steps of measuring and picking a defined amount of water to be tested, placing the water into a reaction vessel, adding sulfuric acid so that the mixture can be acidic, or adding sodium hydroxide so that the mixture can be alkaline, then adding a given mass of potassium permanganate solutions, conducting heating reaction for a period of time, so that reducible substances in the mixture are oxidized by potassium permanganate, adding excessive nitrite solutions for conducting reduction on residual potassium permanganate, and then adding hydrochloric acid and ethanol solutions. When ethyl alcohol is added to hydrochloric acid mediums and serves as a catalyst, nitrite can be transformed into NO<2> instantly. Carrier gas is blown into the reaction vessel for loading NO<2> into a gas phase molecular absorption spectrometer, and the watery potassium permanganate content and the watery permanganate index can be obtained through calculation. The method is simple, rapid and convenient in operation step, by using hydrochloric acid and ethyl alcohol as the catalysis solutions, the reaction is greatly accelerated, the testing result is free of tailing peak phenomenon, and errors are minor.
Owner:孙璐
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