The present invention relates to a molecular solar thermal
system (MOST) based on a pair of isomers, comprising in its low energy ground stage primarily a first low-energy isomer which is excitable by
solar light to form a metastable high-energy isomer and in its
high energy state primarily a second metastable
high energy photoisomer generated via photochemical conversion from the
solar light excitable first isomer. Said MOST
system is characterized by high photo
isomerization yields due to the
light driven out-of-equilibrium
isomerization of the first isomer and is further characterized by a superior
thermal stability of the second
high energy photo isomer. This allows a long-term storage of collected
solar light energy without occurrence of spontaneous unwanted back-
isomerization. By applying a particular class of, optionally immobilized, strong basic catalysts, the stored
solar energy is released in a controlled manner in a catalytic thermalback reaction to yield the low energy first isomer. This offers the possibility of establishing a
cyclic process for repeatedly converting solar
light energy into
thermal energy. The present invention also provides methods of storing
solar thermal energy, methods of releasing stored
solar thermal energy, methods of reversibly storing
solar thermal energy as well as particular solar
thermal energy storage devices comprising the use of the above mentioned MOST pair of photoisomers. The present invention also relates to the use of such compounds for the reversible storing of
solar energy. Further aspects of the present invention relate to a solar
thermal energy capture device, a combined device for capturing solar thermal energy and solar photoelectric energy, as well as a device for operating a reversible MOST
system of the present invention. In addition, the present invention relates to particular novel low and high energy photoisomers applicable in a MOST system of the invention.