A chemical sensor that includes, in one example embodiment, a dielectric resonator, wherein a material sample to be characterized is positioned a species to be detected, wherein the species is positioned near a surface of the resonator so that evanescent electromagnetic energy emanating from the surface causes Raman scattering from the species. The resonator is adapted to support modes propagating within the resonator, wherein the modes are adapted to yield the evanescent electromagnetic energy and to couple Raman-scattered electromagnetic energy back into one or more of the modes. In a more specific embodiment, the dielectric cavity represents a stable optical resonator. An input coupling optic couples input electromagnetic energy into the dielectric cavity via photon tunneling across a gap between the input coupling optic and the dielectric cavity. A distance across the gap is approximately one wavelength or larger, wherein the wavelength corresponds to a wavelength of the input electromagnetic energy. An output coupling optic is adapted to couple one or more modes within the dielectric cavity that contain electromagnetic energy corresponding to the Raman-scattered electromagnetic energy, and to provide an output signal in response thereto.