The invention belongs to the technical field of packaging preparation of light-emitting diode (LED) luminescent materials, and relates to a quantum dot wrapped phase-change paraffin microcapsule, an LED device and preparation methods of the phase-change paraffin microcapsule and the LED device. The quantum dot wrapped phase-change paraffin microcapsule comprises quantum dots, phase-change paraffinand methyl methacrylate-methacrylic acid copolymer shell material, wherein the quantum dots are dispersed and wrapped in the phase-change paraffin which is used as a spherical core of the microcapsule, and the methyl methacrylate-methacrylic acid copolymer outer shell coats the outer surface of the phase-change paraffin wax in a spherical shell shape. The LED device which contains the quantum dot-wrapped phase-change paraffin microcapsule comprises LED lamp beads and a colloid fluorescent coating, wherein the colloid fluorescent coating is doped with the quantum dot-wrapped phase-change paraffin microcapsule, and the colloid fluorescent coating coats light-emitting cup openings of the LED lamp beads. According to the invention, paraffin wax in a liquid state is encapsulated through microcapsules, so that the problem of insufficient scattering performance of quantum dots is solved by optimizing scattering; the surface area is increased through microencapsulation, and heat absorption iscarried out by phase change of the paraffin wax, so that the load of heat dissipation of LED is reduced.