The invention provides a preparation method of a flexible self-supporting Li3VO4 / C
nanofiber lithium ion battery negative
electrode material, which comprises the following steps: adding
lithium nitrate,
ammonium metavanadate and
oxalic acid into a proper amount of N, N-
dimethylformamide, and stirring in a water bath at a constant temperature; meanwhile, taking
polyacrylonitrile to be added into N, N-
dimethylformamide and stirred, then slowly dropping the mixture into the solution, and obtaining a precursor
fiber membrane through electrostatic
spinning; and when the
spinning process is finished, removing the precursor
fiber membrane from the steel roller,
drying, and calcining to obtain the flexible Li3VO4 / C
nanofiber. The flexible self-supporting Li3VO4 / C
composite nanofibers are prepared by combining the electrostatic
spinning technology with high-temperature
solid-phase
sintering for the first time to serve as the negative
electrode material of the
lithium ion battery, the synthesis process method is simple, convenient and easy to operate, a prepared sample does not need an additional binder, a conductive agent and a
current collector and can be directly
cut to serve as an
electrode plate for use, and the material has good mechanical flexibility and shows excellent electrochemical performance.