The invention discloses a preparation method of high-performance modified starch. The method comprises the following steps: putting dry starch into a sealed packet, firstly performing positive surfaceirradiation treatment with low dosage rate on the sealed packet, oxygenating the interior of the sealed packet, shaping the oxygenated sealed packet, and finally performing negative surface irradiation treatment with high dosage rate on the sealed packet, so as to obtain the high-performance modified starch. The method has the advantages that comprehensive irradiation technologies, such as oxygenation, alternative irradiation with different dosage rates, packaging and shaping and overturning, are adopted, so that the irradiation dosage unevenness is smaller than 1.1, the viscosity volatilityof the starch subjected to irradiation modification is smaller than 10 percent, the irradiation efficiency is high, and the cost is reduced.