The invention relates to a stator winding, in particular to a 14-pole and 252-slot asymmetric four-branch two-layer three-phase stator winding. Two layers, namely an upper layer and a lower layer, of wire rods embedded in stator slots are connected at the end parts by a straight end-to-end joint sleeve, an oblique end-to-end joint sleeve and a short copper ring for forming coils in three pitches,by changing winding pitches, and are regularly connected in series for forming four branches, , and the four branches are connected in parallel for forming the stator winding. According to the statorwinding disclosed by the invention, the new asymmetric four-branch two-layer three-phase stator winding which does not meet the condition of a symmetric winding is formed by changing the arrangement law and the connection form of the 14-pole and 252-slot winding. The stator winding disclosed by the invention can not only realize excellent performances of a motor, increase voltage grade, increase the number of the slots which can be selected by a stator of the 14-pole motor and greatly upgrade a motor design technology, but also reduce the axial length of the motor, reduce the height of a factory building and save the construction cost of a power station. The stator winding disclosed by the invention is suitable for 14-pole and 252-slot salient pole synchronous motors, in particular for the field of large-scale water-pumping energy storage motors.