The invention relates to a high-pressure ultraviolet visible near-infrared spectroscopy device for online monitoring of a supercritical system. The high-pressure ultraviolet visible near-infrared spectroscopy device comprises a high-pressure reaction kettle, a controller, an ultraviolet visible near-infrared spectrometer or an ultraviolet visible spectrometer and a computer, wherein the ultraviolet visible near-infrared spectrometer or the ultraviolet visible spectrometer is connected with the computer through a conducting wire, the high-pressure reaction kettle is arranged in a sample bin of the ultraviolet visible near-infrared spectrometer or the ultraviolet visible spectrometer, and the high-pressure reaction kettle is connected with the controller through the conducting wire. The high-pressure reaction kettle is communicated with a high-pressure injection pump and a sample introduction metering pump through a feed valve, a sample pipe and a gas-liquid three-way valve, which are mounted on a pipeline, and communicated with a nitrogen bottle and a vacuum pump through an exhaust valve and a gas three-way valve which are mounted on the pipeline. The high-pressure reaction kettle of the high-pressure ultraviolet visible near-infrared spectroscopy device provided by the invention has the advantages of reasonable design, convenience in use, accurate monitoring and the like, and can be used for online monitoring of physical conversion and chemical reaction processes under supercritical conditions.