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60 results about "Ultraviolet visible spectroscopy" patented technology

Ultraviolet–visible spectroscopy or ultraviolet–visible spectrophotometry (UV–Vis or UV/Vis) refers to absorption spectroscopy or reflectance spectroscopy in part of the ultraviolet and the full, adjacent visible spectral regions. This means it uses light in the visible and adjacent ranges. The absorption or reflectance in the visible range directly affects the perceived color of the chemicals involved. In this region of the electromagnetic spectrum, atoms and molecules undergo electronic transitions. Absorption spectroscopy is complementary to fluorescence spectroscopy, in that fluorescence deals with transitions from the excited state to the ground state, while absorption measures transitions from the ground state to the excited state.

Method and device for measuring sulfur content in coal by ultraviolet absorption spectroscopy

The invention discloses a method and a device for measuring sulfur content in coal by ultraviolet absorption spectroscopy. In the measurement method, the decomposition scale and a threshold are determined adaptively by combining empirical mode decomposition with 3sigma criterion, and non-stationary characteristics of differential absorption degree per se can be fully retained, so the spectral interference problem caused by dust, water vapor and background gas in combustion gas is effectively solved; the instantaneous concentration of SO2 is obtained through calculation according to the differential absorption degree after noise reduction and trend term removal, and the total sulfur content accumulated in the coal sample combustion gas is calculated through the gas flow; the sulfur content in the coal can be obtained by dividing the coal sample amount by the total sulfur content separated from the coal sample combustion; and the pretreatment process needed to be performed on the combustion gas by coulometric titration and an infrared absorption method is avoided. The device for measuring the sulfur content in the coal by the ultraviolet absorption spectroscopy comprises a combustion furnace, a measuring chamber, an ultraviolet light source, a spectrometer, an air purifying device, a flow meter, a waste gas treatment device, a computer, and the like.
Owner:SOUTHEAST UNIV

Pseudo-ginseng and spurious breed thereof identification method based on ultraviolet visible spectroscopy and chemical mode recognition

The invention relates to a pseudo-ginseng and spurious breed thereof identification method based on ultraviolet visible spectroscopy and chemical mode recognition. The method specifically includes: collecting a certain number of pseudo-ginseng and spurious breed thereof, drying, crushing, screening with a 120-mesh sieve, and storing in a sealed plastic bottle; determining testing parameters of an ultraviolet visible spectroscopy instrument, and collecting ultraviolet visible spectra of samples; using a KS method to divide each traditional Chinese medicine, using 2/3 of the samples for training and 1/3 of the samples for predicting, and merging training data of all types into a total training set and predicting data into a total predicting set; determining PLS-DA factor number, building a PLS-DA model, and substituting the spectra of the samples in the predicting set into the PLS-DA model to acquire type of the samples in the predicting set. Spectral data are acquired through an ultraviolet visible spectrophotometer, so that detection is quick, environment-friendly and nondestructive; a PLS-DA method is adopted for modeling to build the model for detecting the pseudo-ginseng and the spurious breed thereof, so that accuracy is high. The identification method is suitable for identifying pseudo-ginseng and the spurious breed thereof.
Owner:TIANJIN POLYTECHNIC UNIV

High-pressure ultraviolet visible near-infrared spectroscopy device for online monitoring of supercritical system

The invention relates to a high-pressure ultraviolet visible near-infrared spectroscopy device for online monitoring of a supercritical system. The high-pressure ultraviolet visible near-infrared spectroscopy device comprises a high-pressure reaction kettle, a controller, an ultraviolet visible near-infrared spectrometer or an ultraviolet visible spectrometer and a computer, wherein the ultraviolet visible near-infrared spectrometer or the ultraviolet visible spectrometer is connected with the computer through a conducting wire, the high-pressure reaction kettle is arranged in a sample bin of the ultraviolet visible near-infrared spectrometer or the ultraviolet visible spectrometer, and the high-pressure reaction kettle is connected with the controller through the conducting wire. The high-pressure reaction kettle is communicated with a high-pressure injection pump and a sample introduction metering pump through a feed valve, a sample pipe and a gas-liquid three-way valve, which are mounted on a pipeline, and communicated with a nitrogen bottle and a vacuum pump through an exhaust valve and a gas three-way valve which are mounted on the pipeline. The high-pressure reaction kettle of the high-pressure ultraviolet visible near-infrared spectroscopy device provided by the invention has the advantages of reasonable design, convenience in use, accurate monitoring and the like, and can be used for online monitoring of physical conversion and chemical reaction processes under supercritical conditions.
Owner:SHAANXI NORMAL UNIV

Gas component detection method and device based on ultraviolet spectroscopy

InactiveCN106018310ADisplay componentsDisplay contentColor/spectral properties measurementsDecompositionUltraviolet
The invention discloses a gas component detection method and device based on ultraviolet spectroscopy. According to the device, an ultraviolet light source is connected with a collimating lens arranged on the outer side of an inlet of a gas absorption cell to provide ultraviolet light during detection; a first concave reflecting mirror arranged on the inner side of the inlet of the gas absorption cell and a second concave reflecting mirror arranged on the inner side of an outlet of the gas absorption cell sequentially reflect collimated ultraviolet light until the ultraviolet light is reflected to a focusing lens; the reflection light reflected sequentially passes by to-be-detected gas injected in advance; a spectrometer performs spectrum analysis on focused reflection light and sends obtained absorption spectra to a data processing device; the data processing device performs comparison and analysis according to the wavelength and power value of input ultraviolet light, gas pressure and temperature of the to-be-detected gas as well as standard diagrams of absorption spectra and prestored gas ultraviolet light absorption spectra and obtains and displays components and content of the to-be-detected gas, and accordingly, the detection efficiency and accuracy of SF6 decomposition components are improved.
Owner:ELECTRIC POWER RES INST OF GUANGDONG POWER GRID

Method for quantitatively analyzing adsorption capacity of stone powder to polycarboxylic superplasticizer by ultraviolet derivative spectroscopy

InactiveCN108872115AReduce the amount of adsorptionEasy to understand the anti-adsorption abilityColor/spectral properties measurementsSide chainSuperplasticizer
The invention discloses a method for quantitatively analyzing the adsorption capacity of stone powder to polycarboxylic superplasticizer (PCs) by ultraviolet derivative spectroscopy. The method comprises the following steps: (1) establishing an absorption spectrum curve of a standard solution by using an ultraviolet visible spectrophotometer; (2) performing second derivative processing of the absorption spectrum curve to extract the ultraviolet characteristic peaks of carboxylic acid of PCs; (3) collecting absorbance A of the solution at the characteristic peaks after blank zero adjustment ofthe spectral curve taking the stone powder and the deionized water system as reference, fitting the relationship formula between the absorbance A and PCs concentrations C by a data statistics method,as working curve, extracting the slope characteristic parameters of the working curve; and (4) according to Langerbeer's law A=KC, determining the change of PCs concentrations by the change of the absorbance values of a filtrate before and after adding stone powder to obtain the adsorption capacity of stone powder to PCs with different side chain lengths. The method is simple in operation, fast inanalysis process, accurate and cheap, and does not require color development.
Owner:NINGBO UNIVERSITY OF TECHNOLOGY

Detection method of content of N-methylimidazole in imidazolium ionic liquid

The invention discloses a detection method of the content of N-methylimidazole in imidazolium ionic liquid. The detection method comprises the following steps: adopting a UV ultraviolet-visible spectroscopy analysis method to prepare the imidazolium ionic liquid and anhydrous ethanol into a 0.1mol/L mixed solution, and by taking an ethanol solution (0.05mol/L) of Cu(II) ions as a complexing color indicator, carrying out UV ultraviolet-visible spectroscopy analysis; according to an obtained maximum absorption peak position lambda max of ultraviolet-visible spectrum, carrying out quantitative analysis on the N-methylimidazole in the imidazolium ionic liquid, wherein for an external standard method standard sample of the imidazolium ionic liquid, an imported high-purity ionic liquid sample is selected. The detection method adopts the simple, convenient and rapid spectroscopy analysis method to carry out qualitative and quantitative analysis, is relatively little influenced by the properties, such as the variety, the viscosity and the conductivity, of the ionic liquid, has the detection range capable of reaching 0-60mol%, is very practical in rapid analysis and detection on the imidazolium ionic liquid, and has very great actual significance of producing the ionic liquid in a large scale.
Owner:LANZHOU INST OF CHEM PHYSICS CHINESE ACAD OF SCI

Regenerated catalyst, regeneration method and application of catalyst, and residual oil hydrogenation method

The invention relates to the technical field of regenerated catalysts, and discloses a regenerated catalyst, a regeneration method and application thereof, and a residual oil hydrogenation method, the catalyst comprises carbon, a carrier and a hydrogenation active metal component loaded on the carrier, the hydrogenation active metal component contains at least one VIB group metal component and at least one VIII group metal component, based on the total amount of the carrier and the hydrogenation active metal component in terms of oxide, the content of the carrier is 30-99 wt%, the content of the VIB group metal component is 0.5-50 wt% in terms of oxide, and the content of the group VIII metal component is 0.5 to 20 weight%; the content of the carbon is less than 3wt% of the content of the carrier; when the regenerated catalyst is measured by diffuse reflection ultraviolet visible spectroscopy (DRUVS), the absorbance at 630 nm and the absorbance at 500 nm are F630 and F500 respectively, and the ratio Q of F630 to F500 is 1-3. The regenerated catalyst provided by the invention has good activity and stability, can be applied to hydrocarbon oil hydrogenation reaction, and is especially suitable for residual oil hydrogenation reaction.
Owner:CHINA PETROLEUM & CHEM CORP +1

A method for measuring wavelength indication error of ultraviolet-visible spectrophotometer

InactiveCN105911008BSolve the measurement problem of arbitrary wavelength indication errorReliable methodColor/spectral properties measurementsFiberLight guide
The invention relates to a measuring method for wavelength indication errors of an ultraviolet and visible spectrophotometer to overcome problems in measurement of any wavelength indication error of the ultraviolet and visible spectrophotometer The method comprises the following steps: calibrating the wavelength of a fiber optic spectrometer and allowing light emitted by the ultraviolet and visible spectrophotometer to converge to light guide inlets of a seven branch-in-one optical fiber via reflection by a reflector lens of a 90-DEG corner lighting device and condensation by a convex lens of the 90-DEG corner lighting device and then to be introduced into the fiber optic spectrometer via the seven branch-in-one optical fiber; and adjusting the location of the 90-DEG corner lighting device in a colorimetric ware groove along a longitudinal direction to allow the spectral energy value of the fiber optic spectrometer to be maximized, fixing a hollow connecting rod into a pressing cap by a tightening a screw, and introducing the light emitted by the ultraviolet and visible spectrophotometer via the 90-DEG corner lighting device and the seven branch-in-one optical fiber into the fiber optic spectrometer for measurement, wherein a difference between the wavelength value of ultraviolet and visible spectrophotometer and a wavelength peak value measured by the fiber optic spectrometer is the wavelength indication error. The method provided by the invention is stable and reliable and has high measuring precision.
Owner:HENAN PROVINCE INST OF METROLOGY +1

Water quality detecting system with standard value comparison function

The invention discloses a water quality detecting system with a standard value comparison function. The water quality detecting system with the standard value comparison function comprises a first spectrum testing unit, a second spectrum testing unit and a power supply; each of the first spectrum testing unit and the second spectrum testing unit comprises a light source, a detecting probe and a spectrometer; the first spectrum testing unit and the second spectrum testing unit are respectively connected with a first industrial computer and a second industrial computer; both the first industrial computer and the second industrial computer are connected with a first master control computer; the first master control computer is connected with each of an alarm device, a first storage module and an instrument control module; the first master control computer is also connected with a second master control computer; the second master control computer is also connected with each of a second storage module, a first display module and a second display module. According to the water quality detecting system with the standard value comparison function, a physical detecting method based on ultraviolet visible spectrum detection is used; the problem of pollution is avoided; the other master control computer is added, so that whether various parameters exceed standards can be calculated and can be judged simply and clearly.
Owner:ANHUI BISHUI ELECTRONICS TECH
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