The invention discloses an 
OLED (Organic Light-Emitting 
Diode)- and OPD (Organic 
Photodetector)-based cascading vertical integration 
capillary electrophoresis chip. The 
OLED- and OPD-based cascading vertical integration 
capillary electrophoresis chip comprises arrayed organic thin-film light sources (OLEDs), a 
polarizer, a multi-channel 
capillary electrophoresis chip, a polarization 
detector and arrayed organic thin-film detectors (OPDs), wherein the OLEDs, the 
polarizer, the multi-channel capillary 
electrophoresis chip, the polarization 
detector and the OPDs are sequentially placed in a parallel and cascading manner; and an upper part and a lower part of each 
electrophoresis channel detection position respectively correspond to the single 
OLED and the single OPD. According to the OLED- and OPD-based cascading vertical integration capillary 
electrophoresis chip, the OLEDs and the OPDs which are made from organic photoelectric materials respectively are adopted, therefore, the easy integration with the multi-channel capillary electrophoresis chip is achieved; with the adoption of planar structural parallel cascading arrangement, the distance between every two devices is small, the optical length of a light path in transmission along the vertical direction is short, the optical loss is effectively lowered, the improvement of 
system sensitivity is facilitated, and the accuracy in detection is improved through the controlling of the 
diameter of an exciting 
light beam by a pinhole; and polaroids which are arranged in a mutually-vertical manner are used for light-filtering, excitation light and 
stray light are effectively filtered out, therefore, the OLED- and OPD-based cascading vertical integration capillary electrophoresis chip is applicable to a detection 
system with wider spectral range.