A multi-barrier coupled treatment process for organic complexed
heavy metals in
wastewater from battery
cathode material production is disclosed, relating to the field of
wastewater treatment. The method involves: 1. Adjusting the pH of the
wastewater to 3.0-4.5; 2. Adding iron salt and
peracetic acid to an oxidation reaction tank; 3. Achieving primary removal of
heavy metals through
neutralization and
precipitation after oxidation; 4. Adjusting the pH of the wastewater back to 6.0-6.5; 5. Passing the wastewater sequentially through a primary adsorption unit and a secondary adsorption unit. This invention utilizes the low
bond energy characteristics of PAA and the synergistic oxidation advantages of multiple free radicals to solve the
bottleneck problems of incomplete complex breaking, large
sludge production, and narrow pH application range in traditional methods.
After treatment by this invention, the total
nickel concentration in the
effluent is less than 0.05 mg / L, and the total
cobalt concentration is less than 0.02 mg / L, consistently exceeding the limits of the "
Emission Standard of Pollutants for Battery Industry" (GB 30484-2013), demonstrating broad industrial application prospects.