The invention provides a long-afterglow luminescent material. The long-afterglow luminescent material is shown as a chemical formula (I): K1-x-y-z-a-bLiaNabGa1-cAlcGe1-dSidO4:xBi<3+>, yM<2+>, zR<3+>, wherein M refers to one or more of Mg, Ca, Sr, Ba and Zn, R refers to one or more of Sc, Y, La, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu, x is not less than 0.0001 and not more than 0.20, y is not less than 0 and not more than 0.20, z is not less than 0 and not more than 0.20, a is not less than 0 and not more than 0.20, b is not less than 0 and not more than 0.20, c is not less than 0 and not more than 0.20, and d is not less than 0 and not more than 0.20. The long-afterglow luminescent material has the advantages that Bi<3+> ions are taken as activation ions and can be activated effectively by ultraviolet light to produce cyan-blue adjustable long afterglow, so that after-glow brightness is high and after-glow lasting time is long.