The invention provides super
fine grain size high light efficiency long lad fluorescent
powder. The chemical
structural formula of the fluorescent
powder is Srm-pMepAl2O(3+m+q):Eux, Dyy, Rz, wherein Me is at least one of Ba and Mg; R is at least one of La and Gd; m is more than 1 and less than or equal to 0.3; p is more than or equal to 0.006 and less than 0.3; q is equal to x plus y plus z; x is more than or equal to 0.005 and less than or equal to 0.05; and z is more than or equal to 0.0001 and less than or equal to 0.01. The preparation method comprises the following steps: 1) by taking the chemical
structural formula of target products as a measuring base, oxides of Sr, Ba, Mg, Eu, Dy, La and Gd and
nitrate or
carbonate are picked up as raw materials; 2) the raw materials are added with reaction auxiliary agent; 3) the
mixed materials are placed in a high-temperature
reducing atmosphere furnace, and subjected to high-temperature synthesis under the protection of N2H2
mixed gas; 4) the sintered fluorescent
powder blocks are crushed to obtain super
fine grain size long lad fluorescent powder; and 5) the crushed fluorescent powder is subjected to aftertreatment to obtain the finished product. The fluorescent powder has the advantages of super
fine grain size and centralized distribution and higher brightness and longer
afterglow time, and can be better applied to fields such as luminescent
fiber, printing,
coating material.