The invention discloses ladle filler sand for continuous-casting high aluminum steel. The sand is formed by evenly mixing, by weight, 29-37% of quartz sand used as skeleton materials, 52-60% of chromium ore used as base materials, 9-12% of carbon powder used as addition agents, and 0.5-2% of phenolic resin used as binding agents. The invention further discloses a use method of the ladle filler sand for the continuous-casting high aluminum steel. The method comprises the steps of firstly conducting roasting pretreatment on the ladle filler sand, then adding the ladle filler sand into a water opening, and enabling the ladle filler sand to exceed5-15mm relative to the plane of a well block of the water opening. By the adoption of the ladle filler sand and the use method, the steel ladle self-opening rate is effectively improved, efficiency is improved, operation is convenient, labor intensity is reduced, the sand is free of pollution and meets the process requirement, in the sand discharging process, the ladle filler sand can smoothly flow out along with molten steel, and slag inclusion in a steel ingot is reduced.