A disclosed PVC color-variable release film comprises PVC, PA, EVA, CPE resin, PBT, PET, methoxy polyethylene glycol, PTFE, polymethyl methacrylate, polyphenylene sulfide, glass fiber, organic montmorillonite, poly(ether ether ketone) fiber, heat-sensitive red, PVA, dodecanol, chitosan, anti-oxidant 1010, light-stabilizing agent 622, nanometer TiO2, PE-g-MAH, a thickening agent and a coupling agent. The release film possesses extremely excellent waterproofness, corrosion resistance, temperature tolerance, weatherability and binding property, also can change color after being heated, and possesses heat-dissipation energy-storage effects.