72results about How to "Preparation Process Green" patented technology

The invention relates to a biology adsorbent and a preparation method thereof as well as application of the preparation method in heavy metal ion adsorption. The biology adsorbent is characterized in that hybrid blending material which has heavy metal ion adsorption capability is prepared by the capability of biological polymer such as microcrystalline cellulose, chitin, chitosan, etc. which can be dissolved in ionic liquid; the ionic liquid is chloridized 1-butyl-3-methyl imidazole salt and chloridized 1-allyl-3-methyl imidazole salt; the preparation of the adsorbent adopts two types: a drying type and a freeze-drying type; the ionic liquid used in the method can be recovered; the prepared adsorbent can be automatically degraded in environment; the preparation method and the prepared adsorbent in the method cause no secondary environmental pollution.

The invention provides a preparation method of a superabsorbent resin used for a high-molecular gel extinguishing agent. The preparation method comprises: mixing acrylic acid and a sodium carbonate aqueous solution to prepare a neutralization solution; successively adding a cross-linking agent, an initiator and an adhesion promoter into the neutralization solution to prepare a polymerization solution; performing polymerization to prepare the superabsorbent resin; and cutting into particles with a diameter of 10-20 mm to further prepare superabsorbent resin particles with a particle size of 40-150 meshes. The preparation method is simple, and the superabsorbent resin prepared by the method is convenient to used and excellent in fire extinguishing effect.

The invention discloses a BrPhinsted acidic ionic liquid which takes multi-ammonium as cation and a preparation method thereof; the ionic liquid is one step prepared through neutralization reaction between multi-ammonium and inorganic acid or organic acid. The invention has the advantages of low cost, simple preparation, green process, and suitability for massive production. The ionic liquid has potential practical application prospect in electronic optical and photoelectric material, energy, resource and environment and life science, etc.

The invention discloses absorbable antibacterial alginate fibers. The alginate fibers are prepared by utilizing a wet-process spinning technology; and after being improved by a cross-linking agent, the fibers have good antibacterial property and have adjustable and controllable biological absorbability. According to the fibers, the preparation method is simple and pollution to the environment cannot be caused; and the alginate fibers have good biological degradation property and antibacterial property, and are expected to be used for a plurality of fields including wound dressings, absorbable surgery suture lines, periodontal regeneration pieces, anti-sticking membranes, absorbable masks and the like.

The invention discloses a preparation method of a silver-loaded nano cellulose-chitosan composite film, the preparation method of the silver-loaded nano cellulose-chitosan composite film comprises the following steps: adding sodium periodate into a nano cellulose solution, stirring in a dark place, centrifuging for separation, and washing to obtain dialdehydo nano cellulose; adding a newly-prepared saturated silver ammonia solution for preparation of silver-loaded nano cellulose; mixing the silver-loaded nano cellulose with a chitosan solution to obtain a silver-loaded nano cellulose-chitosan antibacterial film. Nano silver particles prepared in the method are evenly distributed in dialdehydo nano cellulose network structures, the easy agglomeration problem of the nano silver particles can be well solved, the preparation process does not require the use of special instruments, also does not need a chemical reducing agent, and the production cost is reduced. Through use of good mechanical properties of the nano cellulose, the low mechanical strength problem of the chitosan film is improved, and the antibacterial property of the chitosan film is improved by silver loading operation. The silver-loaded nano cellulose-chitosan composite film has broad application prospects in antibacterial wound dressings and food packaging and other industries.

The invention discloses a composite particle with multiple core-shell structures. The composite particle uses inorganic silica nanoparticles as a core, uses an organic acrylate polymer as a middle layer, and uses a carbon nanotube adsorption layer as a shell. The invention also discloses a preparation method for the composite particle, first nano-silica is synthesized through a Stober method, thenthe surface of nano-silica is coated with an acrylate polymer layer based on a dispersion polymerization method, and an initiator that can be subjected to hydrolytic ionization is used to achieve coating of the nano silica surface with the polymer and charge modification in one step, then further carbon nanotubes are adsorbed through electrostatic self-assembly. The invention provides the composite particle with multiple core-shell structures and the preparation method thereof, the preparation process is green and efficient, and does not need complicated functional modification, and the prepared composite particle has excellent overall performance.

The invention discloses a two-layer crystal whisker-shaped fluorine-doped hydroxyapatite coating on magnesium alloy and a microwave preparation method thereof, and belongs to the technical field of degradable magnesium alloy implantation materials. The fluorine-doped hydroxyapatite coating is of a two-layer structure. The length and diameter of the bottom-layer fluorine-doped hydroxyapatite crystal whisker is 0.5-0.8 micrometer and 50-70 nm respectively. The length and diameter of the top-layer fluorine-doped hydroxyapatite crystal whisker is 1.0-2.0 micrometers and 30-50 nm respectively. The microwave preparation method mainly comprises the steps that a conversion coating solution containing Ca2+, PO43- and F- is prepared, and magnesium alloy subjected to alkali treatment is placed in the conversion coating solution and subjected to microwave heating for 10-30 min. The microwave preparation method is applicable to magnesium alloy of any shapes and sizes, the technology is simple, energy is remarkably saved, and the application and popularization value is huge.

The invention discloses fluorescence amino carbon quantum dots, and a preparation method and application thereof. The preparation method comprises the following steps: (1) mixing aqua ammonia with purified xylan, and stirring until the xylan is dispersed in the solution; (2) transferring the mixture into a reaction kettle, putting in a sealed muffle furnace, and carrying out hydrothermal treatment; (3) cooling the product to room temperature, and carrying out ultrasonic dispersion treatment; (4) carrying out refrigerated centrifugal separation on the treated product, removing the precipitate, and collecting the supernate to obtain a fluorescence amino carbon quantum dot water solution; and (5) concentrating the product water solution by rotary evaporation, and finally, carrying out vacuum drying to obtain the fluorescence amino carbon quantum dots. The amino carbon quantum dots have the advantages of high fluorescence, high stability, low cytotoxicity and favorable biocompatibility, and can be widely used in the fields of cell imaging, disease diagnosis, drug transfer and the like.

The invention discloses a method for preparing ellagic acid by solid fermentation with granatum as a raw material and belongs to the field of medicines and health-care products. In the method, solid fermentation is performed by using a culture medium which takes granatum as a main ingredient and by using Aspergillusniger 3.316 as a fermenting bacterial strain. The conditions for the solid fermentation of the granatum include: the pH value is between 5 and 7; and the granatum is initially moisturized by water by 47 to 60 percent, 0.5-percent NH4NO3 is added into a moisturizing agent as an N source, and fermentation is performed at 30 DEG C for 5 to 7 days. The fermented product is purified and dehydrated to produce the high-quality ellagic acid product. The granatum serving as a raw material is cheap, and the high yield and purity of the ellagic acid product are ensured; and the method has an outstanding cost advantage and is suitable for large-scale production.

The invention relates to an instant selenium-enriched sweet potato solid beverage and a preparing method. The instant selenium-enriched sweet potato solid beverage is characterized in that the instant selenium-enriched sweet potato solid beverage comprises, by weight, 50-90% of sweet potato extractives, 1-50% of konjac glucomannan, 1-5% of stevia, 0.5-3% tea polyphenol and 0.001-0.1% selenium-enriched yeast. The preparing method of the instant selenium-enriched sweet potato solid beverage comprises the following main steps of (a) blending materials and (b) carrying out drying and pelletizing. A preparing method for the sweet potato extractives comprises the following main steps of (a) raw material fluid preparation, (b) sedimentation and centrifugation, (c) separation and (d) concentration. Compared with the prior art, the instant selenium-enriched sweet potato solid beverage is a natural product, is rich in nutrition ingredients, and contains rich sweet potato alkaloid and mineral nutrition. According to the instant selenium-enriched sweet potato solid beverage and the preparing method, waste materials can be changed into valuable things, and the effluent discharge in the production process of sweet potato starch can be reduced in a large scale.

A preparation method for pyro-vanadic acid zinc hollow microsphere comprises the following specific steps of respectively weighting zinc oxide, vanadium oxide, ethylenediamine tetraacetic acid and polyethylene glycol according to weight ratio of (4-6.6):(10-12.6):(1.2-1.6):1; adding the raw material into distilled water of the same weight of 40-50 parts of zinc oxide, stirring at room temperature, thus obtaining mixed liquor after ultrasound; putting the mixed liquor into a self-generated pressure hydrothermal reaction kettle, carrying out constant temperature hydrothermal reaction for 10-15 hours at 160-170 DEG C, then naturally cooling down to room temperature, finally filtering, washing, and drying substrate at the bottom of the kettle so as to obtain breen pyro-vanadic acid zinc hollow microsphere powder for sewage treatment. The preparation method has no secondary pollution and has low raw material cost, the defect of the TiO2 taken as traditional photocatalyst in practical application of sewage purification is effectively overcome by the pyro-vanadic acid zinc hollow microsphere as the photocatalyst, the whole process of the method is simple, the manufacture cost is lower, the method has high feasibility, and is applicable to industrialized mass production of photocatalyst.

The invention provides a method for preparing a superabsorbent resin used in a polymer gel fire extinguishing agent, comprising: mixing acrylic acid with sodium hydroxide or sodium carbonate aqueous solution to prepare a neutralizing liquid; Crosslinking agent, initiator and adhesion promoter to prepare polymerization solution; polymerize to obtain super absorbent resin; cut into particles with a diameter of 10-20mm and further make super absorbent resin with a particle size of 40-150 mesh particles. The method has simple process, and the superabsorbent resin prepared by the method is convenient to use and has excellent fire extinguishing effect.

The invention discloses a T-Nb2O5 / egg white carbon composite material used for a lithium ion supercapacitor as well as a preparation method thereof. The preparation method comprises the following steps: adding ammonium niobate oxalate hydrate into water, stirring, then adding into egg white, dropwise adding diluted hydrochloric acid and then continuously stirring until solution becomes milk white,performing hydrothermal reaction, filtering and then performing freeze drying, then annealing in a nitrogen atmosphere, and finally performing cleaning, drying and grinding, so that the electrode material is obtained. The material can effectively alleviate stacking and agglomeration of Nb2O5 nanoparticles, so that effective specific surface area of the material is increased and utilization rate of an active material is improved; a carbon material generated after high temperature annealing is performed on the egg white rich in nitrogen and oxygen elements can improve wettability and conductivity of the composite material; and a porous structure is beneficial to promotion of rapid transmission and diffusion of ions inside an electrode, so that rate performance and cyclic stability of the electrode material are improved.

The invention relates to the technical field of polyvinyl chloride heat stabilizers, in particular to an arginine metal complex, a compound heat stabilizer and an application thereof. The compound heat stabilizer comprises components as follows: 2-6 phr of an arginine metal complex, 0-0.9 phr of arginine, 0.3-0.9 phr of an auxiliary stabilizer, 0.4-1.2 phr of a lubricant and 0.4-1.2 phr of an antioxidant. The arginine metal complex is used as a main stabilizer of the compound heat stabilizer for PVC and has good initial whiteness and long-term stability, and the mechanical performance and apparent quality of a PVC product can be improved. The PVC product using the compound heat stabilizer has good initial whiteness and long-term stability, excellent heat stabilization effect and good industrial prospects.

The invention discloses a method for preparing 1-deoxynojirimycin (1-DNJ) from mulberry twigs through solid fermentation, and belongs to the field of medicines and healthcare products. According to the method, a culture medium, which is mainly composed of mulberry twigs, is adopted; bacillus subtilis 20632 is taken as the fermentation strain to carry out solid fermentation; wherein the mulberry twig solid fermentation conditions are as follows: pH value is 6.6-9.2; water, which is used to wet mulberry twigs, accounts for 40 to 65% of the total weight of mulberry twigs; 1.5 % of lactose and 1.5 % of peptone are added into the wetting liquid and taken as the carbon source; and the solid fermentation lasts for 2 to 5 days at a temperature of 37 DEG C. After fermentation, the fermentation product is subjected to extraction, membrane filtration, condensation, and drying so as to obtain high quality 1-DNJ. The solid fermentation method has the advantages of high yield, high purity product, low cost, and suitability for large scale industrial production.

The invention relates to a silica gel-graphene-liquid metallic composite and a preparation method thereof. The silica gel-graphene-liquid metal metallic composite is prepared from the following raw materials in parts by weight: 80-110 parts of liquid silica gel, 10-20 parts of fluorinated graphene, 50-70 parts of liquid metal, 5-10 parts of carbon nano-tubes, 5-8 parts of urea formaldehyde, 30-50parts of absolute ethyl alcohol and 0.5-1 part of a dispersion agent. According to the silica gel-graphene-liquid metallic composite, the plasticity of the liquid metal can be effectively improved, and the fluorinated graphene and the carbon nano-tubes are added, so that the material is endowed with excellent mechanical performance and heat-conducting performance, and the preparation technology issimple, convenient, green and easy to operate.

The invention provides a flame-retardant smoke-inhibition light-weight high-strength high-molecular material, and a preparation method thereof. The flame-retardant smoke-inhibition light-weight high-strength high-molecular material comprises following steps: 1, a gelatinizing agent, an oil phase reaction monomer, an oil phase crosslinking agent, an initiator, and a composite flame-retardant smoke-inhibition agent are mixed, and are stirred to be uniform, a dispersion phase is added for emulsification so as to form a uniform fine gel emulsion which is stagnant in upside down position; the gel emulsion is subjected to thermal induced polymerization reaction, and after reaction drying is carried out so as to obtain the flame-retardant smoke-inhibition light-weight high-strength high-molecularmaterial. The flame resistance of the flame-retardant smoke-inhibition light-weight high-strength high-molecular material is capable of reaching V-0 grade or higher only with slightly reduced mechanical performance.

The invention provides fluorescent vegetable fibers and a preparation method thereof as well as fluorescent paper and application thereof and belongs to the technical field of fluorescent paper. The preparation method of the fluorescent vegetable fibers comprises the following steps: providing vegetable fiber pulp; oxidizing the vegetable fibers by utilizing a TEMPO (2,2,6,6-Tetramethylpiperidinooxy) catalytic oxidation system, so as to obtain carboxyl-containing vegetable fibers; then dispersing the carboxyl-containing vegetable fibers in water, and adding a water solution containing rare earth ions, so as to enable the carboxyl-containing vegetable fibers to adsorb the rare earth ions; then adding a precipitation agent and carrying out precipitation; then carrying out post-treatment to obtain the fluorescent vegetable fibers. The method is simple and mild in reaction conditions; no expensive raw materials or instruments are needed and large-scale production can be realized. The prepared fluorescent vegetable fibers are applied to the fluorescent paper, have excellent fluorescence intensity, writability, flexibility and the like and can be used as anti-counterfeiting paper to be applied to a functional packaging material. The utilized natural vegetable fibers can be completely biodegraded and no secondary pollution is caused.

The invention discloses a preparation method and application of K1.33Mn8O16. Manganous salt, sylvite and organic carboxylic acid are mixed with water, and stirring is carried out to perform reaction to obtain sol; drying and dehydration are carried out on the sol to obtain gel; the gel is calcined to obtain the K1.33Mn8O16. The preparation method is simple, convenient and easy to operate, and has the advantages of green, environmental-friendliness, safety and low cost. When the prepared K1.33Mn8O16 is used as an electrode material for making a super capacitor electrode, the super capacitor electrode shows highly-reversible potassium ion intercalation-deintercalation behaviors and rechargeable and dischargeable performance, can obtain a specific capacitance of 110F g<-1> under a voltage of 0 to 1.2V, and has the advantages of good reversibility and wide working potential window.

The invention discloses a reduced oxide graphene-beta-cyclodextrin aerogel adsorbing material and a preparation method thereof. The specific preparation method disclosed by the invention comprises the following steps: firstly, carrying out ultrasonic treatment on a graphite oxide solution to prepare oxide graphene; secondly, adding beta-cyclodextrin and ammonia water into the oxide graphene and then stirring at room temperature; thirdly, adding ascorbic acid and then carrying out ultrasonic reaction; finally, putting the obtained mixture into a water bath kettle, carrying out water bath reaction, and carrying out freeze drying after the reaction is ended, thus obtaining the oxide graphene-beta-cyclodextrin (RGO-beta-CD) aerogel. The preparation method disclosed by the invention has the beneficial effects of simple preparation technology, easiness in controlling conditions, low cost and suitability for large-scale and batch production.

The invention discloses a method for preparing ellagic acid by solid fermentation with granatum as a raw material and belongs to the field of medicines and health-care products. In the method, solid fermentation is performed by using a culture medium which takes granatum as a main ingredient and by using Aspergillusniger 3.316 as a fermenting bacterial strain. The conditions for the solid fermentation of the granatum include: the pH value is between 5 and 7; and the granatum is initially moisturized by water by 47 to 60 percent, 0.5-percent NH4NO3 is added into a moisturizing agent as an N source, and fermentation is performed at 30 DEG C for 5 to 7 days. The fermented product is purified and dehydrated to produce the high-quality ellagic acid product. The granatum serving as a raw material is cheap, and the high yield and purity of the ellagic acid product are ensured; and the method has an outstanding cost advantage and is suitable for large-scale production.

The invention discloses an RGO-beta-CD hydrogel adsorption material and a preparation method thereof. The RGO-beta-CD hydrogel adsorption material is a hydrogel formed by cyclodextrin and graphene oxide. The preparation method specifically comprises the following steps that after a graphite oxide solution is subjected to ultrasonic treatment to prepare graphene oxide, beta-cyclodextrin and 25wt% ammonia water are added, and then stirring is conducted at room temperature for 20-40 minutes; then ascorbic acid is added, stirring is conducted at room temperature for 20-40 minutes, and a mixed solution is obtained; finally, the mixed solution is subjected to a water-bath reaction at 85-95 DEG C for 10-14 hours and is soaked with ionic water after the reaction is finished, water changing is conducted for several times during soaking, and the RGO-beta-CD hydrogel is prepared. The prepared RGO-beta-CD hydrogel adsorption material is simple in preparation process, low in cost, and suitable for large-scale and mass production, and the conditions,are controlled easily.

The invention discloses a planar junction perovskite solar cell and a fabrication method thereof. The planar junction perovskite solar cell comprises a substrate, a titanium dioxide layer, a perovskite light absorption layer, a hole transmission layer and a silver electrode layer which are sequentially laminated, wherein the titanium dioxide layer is a of a compact layered structure. An ultrathin anatase type titanium dioxide nanocrystal is used as an electron transmission compact layer of the perovskite solar cell, so that the application of a mesoporous titanium dioxide layer is reduced, the device structure of the perovskite solar cell is optimized, a low-temperature annealing process (less than or equal to 120 DEG C) of the cell is achieved, and the purposes of more greenness, simplicity and cost reduction of the battery fabrication process are achieved.

The invention discloses a photo-curing organic silicon liquid coating material as well as a preparation method and application thereof. The photo-curing organic silicon liquid coating material is prepared by taking linear polysiloxane, silicon resin, white carbon black and mercaptosilane as main raw materials. The mercaptosilane is subjected to condensation reaction with hydroxyl on the white carbon black through alkoxy on the mercaptosilane, so that the white carbon black is modified, structured agglomeration of the white carbon black due to the fact that the white carbon black contains a large amount of hydroxyl can be prevented, the surface of the white carbon black can contain high-activity mercapto, and cross-linking reaction between the white carbon black reinforcing agent and an organic silicon matrix is achieved. Meanwhile, active sulfydryl of sulfydryl silane and vinyl of linear polyorganosiloxane are subjected to click chemistry under ultraviolet irradiation to achieve normal-temperature cross-linking curing, so that the bottleneck that an existing organosilicone coating material needs a high-temperature condition for cross-linking curing is solved, and the energy consumption can be obviously reduced; meanwhile, thermal decomposition of the heat-sensitive material due to high temperature and residue of impurities such as decomposers and the like in the cross-linking and curing process can be reduced, and the coating material is endowed with more excellent mechanical, insulating and weather-proof properties and the like.

The invention provides a preparation method of a magnetic reduced graphene oxide-beta-cyclodextrin adsorption material. The method includes steps of: performing ultrasonic reduction to the graphene oxide and successively adding a FeCl2 solution, beta-cyclodextrin, ammonia water and ascorbic acid, mixing and uniformly stirring the solution, adding the solution into a container to perform a water bath reaction in a water bath pot at 80-120 DEG C in order to produce the magnetic reduced graphene oxide-beta-cyclodextrin adsorption material. The preparation method has simple process and controllable conditions, is low in cost, and is suitable for large-scale batch production.

The invention relates to a method for preparing a layered double hydroxide (LDH) closing film layer on the surface of magnesium alloy. According to the method, anodized magnesium is directly used as a magnesium source, and the LDH closing film layer is grown in situ on the surface of the anodized magnesium alloy through in-situ growth fluid. Holes in the surface of a magnesium alloy anodized film can be effectively closed, direct contact between corrosive media and a magnesium alloy substrate is avoided, the thickness of a protection layer is increased, and the corrosion resistance of the protection layer is obviously improved. An inorganic salt type reagent is adopted as the reagent of the method, environmental friendliness is achieved, and the reagent is sold in the market, so that the cost is low.

The invention relates to a method for preparing an integrated battery cell. The method is characterized by comprising spraying colloidal substances onto the positive electrode piece and the negative electrode piece of a battery to form a colloidal bonding layer; assembling an individual cell in the order of positive electrode piece / colloidal bonding layer / diaphragm / colloidal bonding layer / negativeelectrode piece; drying the individual cell; spraying the colloidal substance sprayed between two or more layers of dry individual cells to form the colloidal bonding layer, and forming a multilayercell by drying and bonding. The method introduces a polar group onto the surface of the diaphragm to increase the polar electrolyte absorption and retention properties of the diaphragm. The binder improves the mechanical property of the diaphragm and the safety performance of the battery. The method has a green preparation process and a simple operation process, and is suitable for industrial applications.