The invention discloses a normal atmosphere chemical ionization source for surface desorption of a velocitron. A capillary and a spray point arranged in the capillary constitute a reagent ion generation system. When the reagent admitted through the capillary is sprayed out from one end of the capillary, the reagent is ionized to generate ions of the reagent due to the corona discharge of a discharge electrode; the reagent ions impact specimens inside a specimen disc to ionize the specimens, and the specimen ions are admitted into the velocitron inlet capillary to be used for detection. The ionization source disclosed by the invention is equipped with a moving interface, which can be connected with common velocitrons, such as LCQ, LTQ, TSQ and so on, so that the ionization source can be upgraded and become more powerful. The invention achieves quick and sensitive measurement of complicated basal body specimens by adopting the surface desorption atmospheric pressure chemical ionization mass-spectrometric technique under the condition that sample pretreatment is not required. In addition, the invention is applicable for real-time on-line non-destructive analysis in situ during industrial or environmental course. The ion source is joined with related velocitrons, and can achieve different detection modes, such as cation detection, anion detection, free radical ion detection and soon, according to the properties of specimens.