The present invention discloses a laser-assisted cold spray coating method and a nozzle apparatus. According to the nozzle apparatus, one side of the nozzle throat portion is a nozzle constriction section, the other side of the nozzle throat portion is a nozzle expansion section, the nozzle side on the nozzle constriction section is provided with a high pressure gas inlet and a light transmittance window for entering of a laser beam, the light transmittance window deviates from the axis line of the nozzle, the nozzle on the nozzle constriction section is provided with a reflecting mirror A, the nozzle side on the nozzle expansion section is provided with a powder inlet, a reflecting mirror B, a reflecting mirror C and a reflecting mirror D, a laser beam entering from the light transmittance window sequentially passes through the reflecting mirror A, the reflecting mirror D, the reflecting mirror B and the reflecting mirror C in the nozzle and then is emitted from the nozzle expansion section, and the powder inlet is positioned between the reflecting mirror D and the reflecting mirror B; and according to the technical scheme, the laser is incident onto the reflecting mirror in the nozzle in a certain angle forming with the nozzle axis line, and the light beam is subjected to multiple reflections through the reflecting mirrors on the inner wall of the nozzle and finally irradiates on the substrate, such that the gas, the powder and the substrate inside the nozzle can be uniformly pre-heated.