The invention belongs to the technical field of optoelectronic devices and relates to a preparation method of an ultra-thin double-glass photovoltaic module and a product thereof. Specifically, the method of the present invention comprises the following steps of (1) setting an upper layer glass and an upper layer packaging film and adding a head strip film between the upper layer glass and the upper layer packaging film, (2) setting an insulating back sheet, a battery string and a bus bar, (3) setting a lower layer packaging film and adding a tail block-shaped film, a tail strip-shaped film, ahead block-shaped film and a bus bar bending block-shaped film between the battery string and the lower layer packaging film, (4) setting lower layer glass and obtaining a laminated assembly, (5) laminating the laminate assembly, and (6) carrying out chamfering, installing a junction box and connecting a lead-out wire. According to the preparation method of the invention, the problems of air bubbles, delamination, lack of glue, and series and parallel extension in the production process of the ultra-thin double-glass photovoltaic module are solved, and the production efficiency and the yieldof the module are improved.