The invention relates to a WSN mine safety monitoring system with a recombination function and a downhole accident monitoring method, belonging to a mining safety monitoring technology. The invention overcomes the problems of the previous wired monitoring system such as complicated wiring, failure to dynamically follow up an excavating surface, easy damage and the like. In the invention, a ground monitoring center of the monitoring system is an Ethernet system composed of a downhole monitoring access mainframe, a database server, a monitoring terminal and a remote terminal; a downhole wired sensor network is a CAN bus network composed of a plurality of wired sensors; the CAN bus network is connected with the downhole monitoring access mainframe; and a downhole wireless sensor network is composed of gateway nodes, a plurality of cluster-head nodes, a plurality of wireless sensor nodes and a plurality of movable nodes, wherein, the gateway nodes are connected with a CAN bus of the downhole wired sensor network. In addition, after a fault occurs, the gateway nodes and wired sensor nodes can form a higher-level wireless communication network so as to guarantee communication reliability. The invention is applicable to various mines.