The invention discloses a solar light-sensitive road lamp with a thermal siphon cooling system. The road lamp comprises a lamp post, an LED lamp assembly, a switch assembly, a light sensation assembly, a solar cell panel, a controller and a lithium battery assembly, wherein the LED lamp assembly, the switch assembly, the light sensation assembly, the solar cell panel, the controller and the lithium battery assembly are connected through a circuit; the LED lamp assembly, the controller, the solar cell panel and the lithium battery assembly are provided with a set of thermo siphon cooling systemwhich is capable of circularly cooling and used for circularly cooling the LED lamp assembly, the controller, the solar cell panel and the lithium battery assembly. According to the solar light-sensitive road lamp with the thermal siphon cooling system, the LED lamp assembly, the controller, the solar cell panel and the lithium battery assembly can be circularly cooled, a good cooling effect is achieved, the service life of the road lamp is prolonged, and the solar energy conversion rate of the solar cell panel is improved.