The invention relates to an ultrahigh basicity low aluminum fluorine-free refining slag and a preparation method and a use method thereof, belonging to the technical field of steelmaking and refining.The refining slag comprises the following chemical compositions by weight percent: 85-95% of CaO, 2-10% of B2O3, 2-10% of MgO, 1-10% of Al2O3 and less than 5% impurities, wherein the content of harmful impurities such as sulfur, phosphorus and the like is as low as possible. The refining slag is prepared by using industrial reagents, namely active lime, boron anhydride, magnesia and aluminium ashto prepare, premelting at 1350-1450 DEG C, cooling, crushing to 2-10mm and performing moisture proof packaging. The slag series can be used for the refining and slag forming of LF, RH and CAS and therefining slag is added in steel ladle in the process of argon blowing after the molten steel preliminary deoxidation and the reduction treatment of the residue of steel ladle. The refining slag of the invention has strong desulphurizing and dephosphorizing abilities and no pollution, the slag inclusion generated through absorption and deoxidation has higher ability, the deoxidation effect of steel is improved, the spreadability is good, the suction and oxidation of the molten steel are reduced, the refining devices do not adhere to slag, the preparation process is simple, and the product is easy to store and use.