The invention relates to anti-scorching CR unvulcanized rubber capable of being stored for a long time at room temperature, a preparation method thereof and a preparation method of an anti-scorching agent. The materials comprise raw rubber, a reinforcing filler, a plasticizer, a vulcanization accelerator, a coupling agent, an anti-aging agent, the anti-scorching agent, an active agent and a processing aid. The preparation method of the unvulcanized rubber comprises the steps of firstly, preparing the materials into a prefabricated rubber sheet; then adding the prefabricated rubber sheet into an internal mixer or an open mill, adding the active agent, the reinforcing filler, the plasticizer, the coupling agent, the anti-scorching agent, other processing aids and the like, mixing at low temperature, and discharging rubber to prepare a first section of rubber compound; and finally, standing and cooling the first section of rubber compound, adding the vulcanization accelerator and the anti-aging agent into an open mill for mixing, fully opening cooling water during open mixing, performing low-temperature thin passing, uniformly mixing, and batching off to obtain the final rubber compound. Through multi-aspect improvement, the generated rubber material not only has excellent scorching safety, but also can be stored for a long time.