The invention relates to a special sampling device for an online chromatographic analysis system to mainly solve problems of bad analytic result accuracy, bad analytic result stability and bad analytic result repeatability caused by middle and high voltage seepage, condensation obstruction, cracking and the like in acquisition and transmission of a sample in present online chromatographic analysis. The device is characterized in that connection pipelines 54, 55, 56 and 57 which can independently control and adjust the temperature are adopted to respectively let samples in reactors 1, 2, 3 and 4 to into six-way valves 21, 22, 23 and 24; and the samples are respectively acquired by quantitative rings 25, 26, 27 and 28, are carried by carrying gases 29, 30, 31 and 32 to enter the shunting introduction port 36 of a gas chromatograph, and are transmitted from a sample outlet to sample tanks 41, 42, 43 and 44 through two-way valves 37, 38, 39 and 40 respectively. The device well solves the problems through above technical scheme, and can be used for the sample acquisition in online chromatographic analysis.