The invention discloses a solar air conditioner system having charging, control and H-bridge inversion. The air conditioner system comprises a solar cell, a solar controller, a storage battery and a variable frequency air conditioner, wherein the solar controller comprises a charging circuit, a control circuit, a lightning prevention circuit and a discharging circuit, the variable frequency air conditioner comprises an inversion circuit, the inversion circuit comprises a fiftieth-first IGBT (Insulated Gate Bipolar Transistor) tube, a fiftieth-second IGBT tube, a fiftieth-third MOS (Metal Oxide Semiconductor) tube, a fiftieth-fourth MOS tube, a fiftieth-first diode, a fiftieth-second diode, a fiftieth-third diode, a fiftieth-fourth diode, a fiftieth-first resistor and a fiftieth-second resistor. By the solar air conditioner system, lightning can be effectively prevented, the safety performance of the system is improved, the activity of the storage battery can be ensured as well as the storage battery is charged, the service lifetime of the storage battery can be prolonged, the charging efficiency of the storage battery can be improved, the power utilization time of the storage battery is prolonged, the solar air conditioner system has favorable automatic-starting capability, an infinite loop state is prevented, and relatively high efficiency is achieved no matter whether a load works in a light-load or heavy-load condition.