The invention relates to the process for preparing TiO2 photo-catalyst carrier on ceramic surface, wherein the compact ceramic carrier material is supported with TiO2 colloidal sol through sol-gal process, the TiO2 colloidal sol is prepared through dissolving butyl titanate or propyl titanate into acids, alcohols and water, washing and drying the finished ceramic carrier into TiO2 colloidal sol for 2-40 minutes, seasoning, sintering the carrying agent with carried colloidal sol in the furnace, elevating the temperature from room temperature to 80-250 deg. C, heat preserving for 10-80 minutes, elevating temperature again to 250-400 deg. C, heat preserving for 20-80 minutes, elevating the temperature to 450-550 deg. C, heat preserving for 40-90 minutes, furnace cooling to room temperature. A stabilized catalytic activity can be achieved by the invention.