14 results about "Silicon phthalocyanine" patented technology

The invention discloses an antistatic polyester fiber and a preparation method thereof, and relates to the field of fibers. When the antistatic polyester fiber is prepared, N, N-dimethylethanolamine reacts with allyl chloride, and then dichloro phthalocyanine silicon is grafted to obtain modified silicon phthalocyanine; polymerizing terephthalic acid, itaconic acid and ethylene glycol, and reacting with fluorescein isothiocyanate and modified silicon phthalocyanine in sequence to obtain modified polyester chips; the preparation method comprises the following steps: reacting phosphonitrilic chloride trimer with 3-hydroxy-5-nitropyridazine, and reducing to obtain a flame retardant; and carrying out melt spinning on the modified polyester chips and a flame retardant, and reacting to obtain the antistatic polyester fiber. The antistatic polyester fiber prepared by the invention has excellent antistatic property, antibacterial property, flame retardance and mechanical property.

The invention relates to the technical field of nano preparations, in particular to self-assembled nanoparticles suitable for NO synergistic phototherapy and a preparation method and application of the self-assembled nanoparticles. The invention provides a novel furazan NO donor-silicon phthalocyanine photosensitizer conjugate or a furazan NO donor-hyaluronic acid conjugate, and a preparation method of the furazan NO donor-silicon phthalocyanine photosensitizer conjugate or the furazan NO donor-hyaluronic acid conjugate. The furazan NO donor-silicon phthalocyanine photosensitizer conjugate is subjected to self-assembly preparation, or the furazan NO donor-hyaluronic acid conjugate wraps a photosensitizer or other drugs to obtain the self-assembly nanoparticles suitable for NO synergistic therapy. The nanoparticle realizes space-time co-transport of NO and the photosensitizer, has a controllable drug release behavior, and improves the tumor treatment effect. The nanoparticles can generate NO and ROS in cells, the NO and the ROS react with each other to form an active nitrogen substance, heat released by phototherapy and ROS promote release of NO, and the nanoparticles and NO cooperate to induce apoptosis of breast cancer cells or cervical cancer cells.

This invention belongs to the field of biomedical materials technology, and relates to a black phosphorus phthalocyanine hydrogel, its preparation method, and its application. The black phosphorus phthalocyanine hydrogel comprises black phosphorus phthalocyanine and a photocurable gel. The preparation method of black phosphorus phthalocyanine includes the following process: under acidic conditions, black phosphorus nanosheets are mixed with aminosilicon phthalocyanine, allowing the black phosphorus nanosheets and aminosilicon phthalocyanine to self-assemble to form black phosphorus phthalocyanine. This invention combines black phosphorus with aminosilicon phthalocyanine; under the action of near-infrared laser, black phosphorus and aminosilicon phthalocyanine can synergistically exert a bactericidal effect. Simultaneously, black phosphorus can degrade, and its product, phosphate, can promote bone tissue regeneration, thus more effectively treating peri-implantitis.

The invention relates to silicon phthalocyanine, a green photosensitive resin composition and application of the silicon phthalocyanine, the silicon phthalocyanine is prepared by substituting a benzene ring site at the periphery of a silicon phthalocyanine mother nucleus or / and a silicon center axial site through a multifunctional group, and the structural formula of the silicon phthalocyanine is as follows: R1-R18 are independently selected from any one of hydrogen atoms, chlorine atoms, alkyl groups, aryl groups or heteroaryl substituent groups; and R1 to R18 at least comprise one naphthalimide group. The green photosensitive resin composition is obtained by mixing a coloring agent, resin containing a double-bond structure or / and an epoxy structure, a monomer containing the double-bond structure or / and the epoxy structure, a photoinitiator with 365nm high absorption characteristic, an additive for improving film-forming property or / and stability, and a solvent containing an ether group. Compared with the prior art, the silicon phthalocyanine has excellent solubility and photo-thermal stability, and the prepared green photosensitive resin composition has high color purity and can be used as a color photoresist for preparing a color filter.

The invention relates to silicon phthalocyanine, a blue photosensitive resin composition and application of the silicon phthalocyanine, the silicon phthalocyanine is prepared by substituting benzene ring sites on the periphery of a silicon phthalocyanine mother nucleus or / and silicon center axial sites through multifunctional groups, and the structural formula of the silicon phthalocyanine is shown in the specification, r1 to R18 are independently selected from any one of a hydrogen atom, a chlorine atom, an alkyl group, an aryl group or a heteroaryl substituent group. The blue photosensitive resin composition is obtained by mixing a coloring agent, resin containing a double-bond structure or / and an epoxy structure, a monomer containing the double-bond structure or / and the epoxy structure, a photoinitiator with 365nm high absorption characteristic, an additive for improving film-forming property or / and stability, and a solvent containing an ether group. Compared with the prior art, the silicon phthalocyanine prepared by the invention has excellent solubility and photo-thermal stability, and the blue photosensitive resin composition can be prepared into a thinner colored layer, has high pigmentation degree, and can be used as a color photoresist for preparing a color filter.

The invention discloses a di-(4-(4-(2-(1, 1-oxyimidoyl) ethyl) piperazine-1-formyl) phenyl) boric acid axial substituted silicon phthalocyanine as well as a preparation method and application of the di-(4-(4-(2-(1, 1-oxyimidoyl) ethyl) piperazine-1-formyl) phenyl) boric acid axial substituted silicon phthalocyanine. A piperazine group is connected to the axial position of silicon phthalocyanine to form piperazine silicon phthalocyanine (PIP-SiPc), then di-(4-(4-(2-(1, 1-oxydiimide) ethyl) piperazine-1-formyl) phenyl) boric acid axial substituted silicon phthalocyanine (PPBA-SiPc) is further synthesized, and the complex is applied to MCF-7 breast cancer cell therapy as an endoplasmic reticulum probe and a photodynamic therapy photosensitizer.

This application relates to a novel A3B type silicon phthalocyanine containing a new silicon tribenzophthalocyanine dye.

The application provides a silicon phthalocyanine J-aggregation film, a preparation method thereof and application thereof in infrared photoelectric detectors. The silicon phthalocyanine J-aggregation film is prepared by dissolving a silicon phthalocyanine shown in formula I in an organic solvent to form a solution, and then performing spin coating, vacuum and high-temperature self-assembly. The application also provides a preparation method of the silicon phthalocyanine J-aggregation film. The J-aggregation film has an obviously increased absorption at near infrared (800-900 nm), and has excellent photoelectric response to near infrared light, which is manifested as high sensitivity and on-off ratio. The silicon phthalocyanine J-aggregation film has low price, simple process and good stability, is a novel organic J-aggregation film, and has extremely strong potential application value in the field of organic near infrared detectors.

The invention relates to silicon phthalocyanine compounds containing pyridine groups with anti-cancer (cancer-therapeutic) and antioxidant effects, which exhibit activity in cancer cells that show resistance to metal-containing compounds, have a broader activity spectrum compared to metal-containing compounds, possess lower toxicity and reduced side effects compared to metal-containing compounds, and can be used as potential anti-tumor drugs, as well as to the methods of synthesis of these compounds.

An electrostatic charge image developing toner includes a toner particle that contains a silicon phthalocyanine dye and a zirconium oxide particle.

This invention discloses a binary phthalocyanine exhibiting type I photosensitivity and photothermal synergistic effects, its preparation, and its applications. The binary phthalocyanine is a silicon phthalocyanine-zinc phthalocyanine coupling compound or a zinc phthalocyanine-zinc phthalocyanine coupling compound, which can self-assemble in water. In water, the self-assembled binary phthalocyanine not only produces an effective type I photosensitivity reaction but also generates a photothermal effect, thus it can be used as a photosensitizer, photothermal agent, or photodynamic-photothermal combined drug. Furthermore, when used as a photodynamic-photothermal combined drug, it can generate a high amount of superoxide anions and a significant photothermal effect under near-infrared laser irradiation and hypoxic conditions, meaning it has high anticancer activity under both aerobic and anaerobic conditions, showing significant application prospects in the treatment of hypoxic tumors. In addition, in vivo experiments have demonstrated that the binary phthalocyanine can be cleared by the kidneys and excreted in urine, effectively avoiding potential biotoxicity caused by drug accumulation after treatment, thereby significantly improving biosafety.

The invention provides a hydroxyapatite composite nanomaterial, preparation thereof and application of the hydroxyapatite composite nanomaterial in antibacterial and antibacterial bone repair drugs. The preparation method of the composite nano material comprises the following steps: fully dissolving calcium nitrate tetrahydrate and polyacrylic acid in deionized water, and adjusting the pH value to 9-10 to obtain a viscous solution; adding a diammonium hydrogen phosphate aqueous solution, and reacting to obtain a suspension; dialyzing the suspension liquid to obtain hydroxyapatite dispersion liquid; and adding a mixed solution of a carboxyl activator, a carboxyl condensing agent, alkali and phthalocyanine, reacting, dialyzing and drying. According to the invention, polyacrylic acid is selected as a polymer medium to help hydroxyapatite crystals to grow and assemble into spherical nanoparticles and prevent aggregation of the spherical nanoparticles, and silicon phthalocyanine is further used for modification to obtain multifunctional nanoparticles, so that the stability and dispersity of the system are improved, and the system has photodynamic therapy and photothermal therapy properties, and has good application prospects. The phototherapy antibacterial bone repair medicine is a novel bone repair medicine with a phototherapy antibacterial effect, can effectively promote osteogenesis and has an excellent antibacterial capability.

According to the silicon phthalocyanine enhanced honeycomb structure and the preparation method and application thereof, silicon phthalocyanine molecules are efficiently loaded in a honeycomb matrix structure, so that the mechanical property, thermal stability and functional characteristics of a material are remarkably improved. The process takes a porous honeycomb as a raw material, silicon phthalocyanine is uniformly dispersed in a matrix skeleton through a sol-gel method polymerization technology, and the process comprises the following specific steps: constructing a honeycomb porous structure through a template-assisted forming process; dissolving silicon phthalocyanine in an organic solvent, and mixing with the matrix precursor to form homogeneous sol; and carrying out gradient heating curing sintering, so that the silicon phthalocyanine and the matrix form chemical bonding. The method has the advantages that by introducing silicon phthalocyanine, the compressive strength (improved by more than 40%) and the high temperature resistance (tolerable temperature reaches 800 DEG C) of the material are greatly improved; the high specific surface area (greater than 200m < 2 > / g) of the honeycomb structure and the catalytic / photoelectric characteristics of silicon phthalocyanine have a synergistic effect, so that the material is endowed with excellent adsorption, catalytic degradation and energy conversion performance.

The invention discloses a di-(4-N-methyl-5-methylthiazole-1-ethyoxyl) axially substituted silicon phthalocyanine diiodide as well as a preparation method and application of the di-(4-N-methyl-5-methylthiazole-1-ethyoxyl) axially substituted silicon phthalocyanine diiodide. The di-(4-N-methyl-5-methylthiazole-1-ethyoxyl) axially substituted silicon phthalocyanine diiodide is prepared from methyl iodide and di-(5-methylthiazole-1-ethyoxyl) axially substituted silicon (IV) phthalocyanine, and the structural formula of the di-(4-N-methyl-5-methylthiazole-1-ethyoxyl) axially substituted silicon phthalocyanine diiodide is shown in the description. The invention also discloses application of the compound as a novel photosensitizer for mitochondrial targeting labeling and fluorescence imaging guided photodynamic therapy in photodynamic therapy.