The invention provides an intermediate
dielectric microwave ceramic material with a near-
zero temperature coefficient and a preparation method thereof, and relates to the field of
ceramic materials. The material comprises the following components in percentage by weight: 97 to 98.5 percent of main
crystal phase, 0.1 to 1.0 percent of Mg-Ca-Si-O glass phase and 0.5 to 2.5 percent of modified additive (selected from BaCO3, SrCO3 and the like), the core
chemical formula of the main
crystal phase is (MxCaLnz) TiO3, and during preparation, Mg / Zn salt, Ca salt,
rare earth and TiO2 are mixed and calcined for 1-4 h at the temperature of 1050-1250 DEG C, and the main
crystal phase is obtained; melting the Mg-Ca-Si-O mixture, and performing water
quenching to obtain a glass phase; the three components are mixed in proportion, molded under 10MPa, and sintered at 1280-1400 DEG C for 2-5 hours. The
room temperature dielectric constant of the material is 25-33, Qf is larger than or equal to 25000GHz, tau f (-40-110 DEG C)-10-30ppm / DEG C is adjustable, the cost is low, the
sintering applicability is high, the requirements of
microwave devices are met, the overall preparation steps are simple, key parameters (temperature, time, pressure and the like) are definite, the
repeatability is good, and the industrial stable production requirements can be met.