This invention provides a
porous carbon-based
nanocomposite material with intrinsically
zero temperature coefficient, its preparation method, and a flexible
pressure sensor with intrinsically
zero temperature coefficient, belonging to the field of flexible pressure-sensitive materials technology. This invention uses PDMS as a flexible matrix and
carbon black and carbon nanotubes as conductive fillers. It innovatively constructs a uniform and controllable pore structure within the material through a chemical foaming method that generates gas by the in-situ reaction of
sodium bicarbonate and
hydrochloric acid. Unlike existing technologies that rely on circuit compensation, this invention achieves precise cancellation of the positive and
negative temperature coefficient effects of the material over a wide temperature range by synergistically controlling the ratio of
carbon black to carbon nanotubes and the
porosity of the material, thus obtaining a
porous carbon-based
nanocomposite material with intrinsically
zero temperature coefficient. The preparation temperature and
energy consumption are low, the process is simple and controllable, and the
relative change rate of the material's resistance is less than 2% in the range of 25~100℃. When used in a flexible
pressure sensor, it does not rely on external compensation circuits and exhibits both excellent piezoresistive sensitivity and temperature stability.