The invention relates to the technical field of welding, and discloses a plasma welding process of duplex stainless steel 2205 with bypass wire feeding, comprising the following process steps: (1) steel plate cutting, (2) welding wire selection, (3) steel plate pretreatment , (4) splicing and positioning of steel plates, (5) installing back protection tooling, (6) filling back protective gas, (7) welding; the welding process parameters are: the polarity of the power supply of the plasma arc welding equipment is DC positive connection, plasma arc welding equipment The tungsten electrode type of the arc welding torch is cerium tungsten electrode WCe‑20, and the diameter is φ4.0mm; the back shielding gas and the welding front shielding gas are a mixture of 98% argon and 2% nitrogen, plasma gas, hood gas It is argon gas with a purity grade of 99.99%; the plasma gas flow rate is 5.5~6.0L / min, the flow rate of the welding front shielding gas and the hood gas are both 25~30L / min, the welding current is 220~240A, the voltage is 26~28V, and the welding speed is 19~21cm / min, heat input 0.98-1.27KJ / mm. The invention can improve welding efficiency, reduce production cost and improve welding quality at the same time.