The invention relates to an anisotropic particle preparation method based on change of hydrophilicities of non-crosslinked seeds. The method comprises the steps: firstly a series of
polymer seeds having different surface hydrophilicities are prepared and then are swollen with monomers incompatible with the
polymer seeds; according to different phase separation degrees of polymers which are induced by different interfacial tensions and incompatible with the seeds, the degree of phase separation is controlled, composite particles with controllable morphologies are obtained, and thus a series of anisotropic composite particles having different micro morphologies are successfully synthesized. The method adopts the
soap-free
emulsion polymerization, takes water as a reaction medium, is different from a conventional method adopting highly crosslinked seeds and various organic solvents as a dispersion phase, can prepare the non-crosslinked composite particles, and is conducive to separation and further
processing. The synthesis process is simple and feasible, is clean and
environmentally friendly, is easy for large-scale production, moreover, has universality, and is applicable to other
polymer systems incompatible with each other.