The invention belongs to the fields of structural design and synthesized preparation of innovative chelate
polymer-material antioxidants and particularly relates to an application of a novel chelate antioxidative stabilizer in a high-
polymer material and a preparation method for the novel chelate antioxidative stabilizer. The novel chelate antioxidative stabilizer acts dual protective actions. Thepreparation method for the chelate antioxidative stabilizer comprises the steps: (1) adding a compound 1 and
epoxy chloropropane, slowly adding
sodium hydroxide or
potassium hydroxide in batches, carrying out a heat-preserving reaction until the compound 1 reacts fully, and adding 1L of MTBE or DCM or DCE, so as to obtain a colorless oily compound 2; and (2) adding thioalcohol, adding a
solvent,carrying out stirring for 30 minutes, adding the compound 2 at the temperature of 5 DEG C to 10 DEG C under
nitrogen protection, carrying out ice-bath treatment for half an hour, and slowly adding
sodium hydroxide or
potassium hydroxide, thereby obtaining a compound 3 or a compound 4. The chelate antioxidative stabilizer not only has a
thioether long-acting high-temperature oxidation resisting activity functional group, but also has the function of forming
sulfur and hydroxyl coordinated five-membered cyclic complexed
metal ions, and this function plays a role in complexed removal of
metal ions catalyzing degradation of the high-
polymer material.