The invention belongs to the field of laser initiating explosive devices, and particularly relates to an optical window based on a double-self-focusing lens structure. The optical window comprises anignition laser, a detection laser, an optical switch, a photoelectric detector, a first self-focusing lens, a second self-focusing lens and a sapphire transparent window, wherein the ignition laser isconnected to the optical switch through an ignition input fiber and a detection input fiber correspondingly, the optical switch is connected with the first self-focusing lens through the ignition optical fiber, the photoelectric detector is connected with the first self-focusing lens through the detection optical fiber, the second self-focusing lens and the sapphire transparent window are sequentially placed behind the first self-focusing lens, and optical axes of the first self-focusing lens, the second self-focusing lens and the sapphire transparent window are coaxial. According to the optical window, the technical defects of an existing laser initiating explosive device optical window are overcome, the laser radiation power density is avoided, a certain proportion of detection light isguaranteed to enter the detection optical fiber, the consistency of the reflectivity of the initiating explosive devices is improved, and the capability of the chamber pressure resistance of the optical window is improved.