The invention relates to a fresh water-electricity co-supply system coupled with a fuel cell residual energy and an absorption water generator, and belongs to the technical field of new energy. It includes a fuel cell stack with an operating temperature of 60-80°C, a first heat exchanger, a second heat exchanger, an auxiliary cooling device, a heat storage device and a fresh water production device; the cathode outlet of the fuel cell stack is connected to the first The inlet of a heat exchanger, the outlet of the first heat exchanger is connected to the port of the high-humidity air channel of the fresh water production device; the fresh water production device includes a salt solution tank and a moisture space; the salt solution tank is provided with a concentration of 85-88 % saline solution; a thermosiphon is provided in the saline solution tank, and a thermosiphon circulation loop is formed between the thermosiphon, the second heat exchanger and the housing of the first heat exchanger; the working medium of the thermosiphon circulation loop is a temperature of 60- It is a substance in a liquid-gas two-phase state at 80°C; using the waste heat of FC, on the one hand, the relative humidity of the input air is increased through high-humidity gas, and on the other hand, the dehydration of the adsorbent is realized, and finally the high-efficiency fresh water-electricity cogeneration efficiency is realized.