This invention discloses an ultra-permeable PTFE microporous
raw material tape for cables and its preparation method, relating to the field of cable materials. The microporous
raw material tape comprises
polytetrafluoroethylene (PTFE), a
propellant, and hydrophobic porous particles. The hydrophobic porous particles are prepared by hydrophobic modification of porous particles with
silane. Each
porous particle includes a core layer and a shell layer; the core layer is
naphthalene, and the shell layer is silica, with a
molar ratio of (2-8):1. This application incorporates hydrophobic porous particles into the PTFE
raw material tape. The
naphthalene in the core layer can volatilize at high temperatures to form hollow particles, which, combined with the micropores of the silica shell layer, improves the air permeability of the raw material tape. When applied to cables, this increases temperature
diffusion efficiency. Simultaneously, the porous particles provide a rigid framework, reducing irreversible deformation and improving
tear resistance. The micropores of the hydrophobic porous particles can block water molecules with
high surface tension, and, combined with the hydrophobic groups on the surface, enhance the water-blocking effect of the raw material tape, meeting the requirements of cable applications.