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61results about How to "Excellent storage properties" patented technology

Non-aqueous electrolytic solution, and non-aqueous electrolyte battery comprising same

Disclosed are: a non-aqueous electrolytic solution which comprises a lithium salt and a non-aqueous organic solvent, and which is characterized in that the non-aqueous organic solvent contains at least one component selected from the group consisting of a saturated cyclic carbonate, a linear carbonate and an aliphatic carboxylic acid ester in the total amount of more than 90 vol%, and a fluorine-substituted aromatic ester compound represented by general formula (1) is additionally contained in an amount of 0.01 to 10 wt% relative to the total weight of the non-aqueous electrolytic solution; and a non-aqueous electrolyte battery comprising the non-aqueous electrolytic solution. Xn-Ph-OCOR (1) [In general formula (1), Ph represents a phenylene group; R represents a hydrocarbon group which has 1 to 12 carbon atoms and may be substituted by a fluorine atom; X represents a fluorine atom, or a fluorine-substituted alkyl group having 1 to 12 carbon atoms; and n represents an integer of 1 to 4.] Also disclosed are: a non-aqueous electrolytic solution which comprises an electrolyte and a non-aqueous solvent, and which is characterized by additionally containing a compound represented by general formula (3); and a non-aqueous electrolyte battery comprising the non-aqueous electrolytic solution. [In general formula (3), R1 represents a hydrocarbon group which has 1 to 12 carbon atoms and may be substituted by a fluorine atom; R2 to R6 independently represent a hydrogen atom, a fluorine atom, or an alkyl group which has 1 to 12 carbon atoms and may be substituted by a fluorine atom, wherein at least one of R2 to R6 represents an alkyl group which has 2 or more carbon atoms and may be substituted by a fluorine atom; and n represents an integer of 0 or 1, wherein at least one of R2 to R6 represents an alkyl group which has 5 or more carbon atoms and may be substituted by a fluorine atom when n is 1.]
Owner:MITSUBISHI CHEM CORP

Non-aqueous Electrolytic Solution, And Non-aqueous Electrolyte Battery Comprising Same

A nonaqueous electrolytic solution comprising a lithium salt and a nonaqueous organic solvent, wherein the nonaqueous organic solvent comprises: at least one member selected from the group consisting of saturated cyclic carbonates, linear carbonates, and aliphatic carboxylic acid esters, in a total proportion exceeding 90% by volume; and a fluorine-substituted aromatic ester compound represented by the following general formula (1) in an amount of 0.01-10% by weight based on the weight of the whole nonaqueous electrolytic solution; and a nonaqueous-electrolyte battery including the nonaqueous electrolytic solution. €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒXn-Ph-OCOR€ƒ€ƒ€ƒ€ƒ€ƒ(1) [In general formula (1), Ph is phenylene, and R is a hydrocarbon group which has 1-12 carbon atoms and may have been substituted with a fluorine atom. X is a fluorine atom or a fluorine-substituted alkyl group having 1-12 carbon atoms, and n is an integer of 1-4.] Furthermore disclosed are: a nonaqueous electrolytic solution which comprises an electrolyte, a nonaqueous solvent and a compound represented by general formula (3); and a nonaqueous-electrolyte battery including the nonaqueous electrolytic solution. [In general formula (3), R 1 represents a hydrocarbon group which has 1-12 carbon atoms and may have been substituted with a fluorine atom, and R 2 to R 6 each independently represent a hydrogen atom, a fluorine atom, or an alkyl group which has 1-12 carbon atoms and may have been substituted with a fluorine atom, at least one of R 2 to R 6 representing an alkyl group which has 2 or more carbon atoms and may have been substituted with a fluorine atom. Symbol n represents an integer of 0 or 1. When n is 1, at least one of R 2 to R 6 represents an alkyl group which has 5 or more carbon atoms and may have been substituted with a fluorine atom.]
Owner:MITSUBISHI CHEM CORP

Nonaqueous electrolyte solution and lithium secondary battery using same

Disclosed is a nonaqueous electrolyte solution which is excellent in battery characteristics such as battery capacity, cycle characteristics and storage characteristics and is capable of maintaining adequate battery performance for a long time. Also disclosed is a lithium secondary battery using such a nonaqueous electrolyte solution. Specifically disclosed is a nonaqueous electrolyte solution for lithium secondary batteries wherein an electrolyte salt is dissolved in a nonaqueous solvent. This nonaqueous electrolyte solution contains 0.1-10% by weight of an ethylene carbonate derivative represented by the general formula (I) below, and 0.01-10% by weight of a triple bond-containing compound (A) and / or a pentafluorophenyloxy compound (B) represented by the general formula (X) below. Also specifically disclosed is a lithium secondary battery using such a nonaqueous electrolyte solution. [Chemical formula 1] (I) (In the formula (I), R<1>-R<3> respectively represent a hydrogen atom, a halogen atom, an alkenyl group, an alkynyl group or an aryl group. In this connection, ethylene carbonates are excluded.) [Chemical formula 2] (X) (In the formula (X), R<15> represents an alkylcarbonyl group, an alkoxycarbonyl group, an aryloxycarbonyl group or an alkanesulfonyl group.
Owner:MU IONIC SOLUTIONS CORP
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