The invention discloses a device for evaluating the performance of an SCR catalyst for synergistically removing nitric oxide, benzene and methylbenzene. The device comprises a first gas distribution system, an NH3 gas distribution system, a gas mixing system, a temperature control system, a reaction system and an analysis system which are respectively in electric control connection with an instrument control system, wherein the first gas distribution system, the gas mixing system, the reaction system and the analysis system are sequentially arranged and connected from upstream to downstream along a gas path, the NH3 gas distribution system is connected with the reaction system, and the temperature control system is respectively connected with the gas mixing system and the reaction system.According to the invention, the denitration performance and the volatile organic compound removal performance of the SCR catalyst can be simultaneously detected, the safety is high, the temperature window is wide, the flow rate is adjustable, the proportion selectivity of each pollutant component is high, the application range is wide, the reliability is good, and the performance of the SCR catalyst for synergistically removing nitric oxide, benzene and toluene can be detected on line.