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30 results about "Membrane gas separation" patented technology

Gas mixtures can be effectively separated by synthetic membranes made from polymers such as polyamide or cellulose acetate, or from ceramic materials. While polymeric membranes are economical and technologically useful, they are bounded by their performance, known as the Robeson limit (permeability must be sacrificed for selectivity and vice versa). This limit affects polymeric membrane use for CO₂ separation from flue gas streams, since mass transport becomes limiting and CO₂ separation becomes very expensive due to low permeabilities. Membrane materials have expanded into the realm of silica, zeolites, metal-organic frameworks, and perovskites due to their strong thermal and chemical resistance as well as high tunability (ability to be modified and functionalized), leading to increased permeability and selectivity. Membranes can be used for separating gas mixtures where they act as a permeable barrier through which different compounds move across at different rates or not move at all. The membranes can be nanoporous, polymer, etc. and the gas molecules penetrate according to their size, diffusivity, or solubility.

Water treatment system and method

The invention discloses a water treatment system and method. The system comprises a water quality monitoring device, a water quality evaluating device and a water body purifying device, wherein the water quality monitoring device is installed in a water body to be detected and used for obtaining various physical, biological and chemical indexes of the water body to be detected; the water quality evaluating device is used for comparing the various physical, biological and chemical indexes obtained by the water quality monitoring device with the water quality standard to determine whether the water body needs to be treated or not; the water body purifying device is arranged on the water quality monitoring device to be communicated and used for receiving the water body which is determined by the water quality evaluating device and needs to be treated and purifying the water body through at least one treatment device. According to the film and gas separation technology, by applying the film diffusion principle, poisonous and harmful ammonia nitrogen and carbon dioxide in aquatic products in the water body are removed in a physical mode, chemical and biological removal are avoided, the system is applicable to the fast-pace business traffic, and no other chemical matter in the water body is added.
Owner:宁波琅华泰阁海洋科技有限公司

Membrane gas separation plant and method for operating same

A method is proposed for operating a plant for purifying a high-pressure gas mixture from easily permeating components, which plant comprises membrane gas separating units having a high-pressure chamber and a low-pressure chamber with a selectively permeable membrane therebetween, in which method the low-pressure chamber of at least one membrane gas separating unit is continuously flushed with purified gas mixture (semi-finished product or product), wherein the pressure difference between the aforementioned chambers of the membrane gas separating unit and, likewise, the flow rate of the purified gas mixture used for flushing are maintained so that the amount of each easily permeating component in the product does not exceed the desired values. The proposed method makes it possible to purify a raw material (high-pressure gas mixture) from one or more easily permeating components simultaneously (in particular helium, hydrogen sulphide, mercaptans, carbon dioxide, water and / or heavy hydrocarbons), increase purification efficiency (i.e. the ratio between the total area of the selectively permeable membrane in the plant, the productivity of said membrane and the specific energy consumption of the gas separation process), and provide the possibility of using (treating or preparing) raw material with a higher content of easily permeating components.
Owner:"盖瑞斯"股份有限公司

A self-polymerized microporous polyimide gas separation membrane and its preparation method and application

The invention relates to a self-polymerized microporous polyimide gas separation membrane and its preparation method and application, belonging to the technical field of membrane gas separation, in order to prepare and synthesize a polymer gas separation membrane with high selectivity and high permeability , to meet the requirements of practical industrial applications. In the present invention, the main chain of self-polymerized microporous polyimide contains a ladder structure, which increases the distance between polymer chains, facilitates the separation and diffusion of gases, and reduces the hydrogen bonds between polymer molecules. function, improve the solubility of the polymer, the present invention utilizes two kinds of diamines with ladder structure and dianhydrides with different structures to prepare through homopolymerization or copolymerization reaction. In the present invention, two kinds of ladder-shaped diamine monomers containing oxa-naphthalene structure were synthesized for the first time, and the trapezoidal self-polymerizing microporous polyimide polymer containing oxa-naphthene structure was synthesized through polycondensation reaction, which has good thermal stability and Mechanical properties, high selectivity to oxygen / nitrogen, can meet the practical application of gas separation.
Owner:SHANXI INST OF COAL CHEM CHINESE ACAD OF SCI

Method of Fractionating Mixtures of Low Molecular Weight Hydrocarbons

The invention relates to the field of membrane gas separation and can be used for the energy-efficient fractionation of hydrocarbon mixtures, including separation and drying of natural and associated petroleum gases. Proposed is a method of fractionating mixtures of low molecular weight hydrocarbons which is based on the capillary condensation of the components of a mixture in the pores of microporous membranes with uniform porosity and a pore diameter in a range of 5 to 250 nm, wherein, for capillary condensation, the temperature of the membrane and the pressure on the permeate side are kept below the temperature and the pressure of the feed mixture such that the equilibrium pressure of the saturated vapors of the separated components on the permeate side is lower than the partial pressure of the components in the feed stream. This method makes it possible to significantly increase membrane permeability with respect to condensable components (over 500 m3/(m2·atm·h) for n-butane), and also component separation factors (the n-C4H10/CH4 separation factor is greater than 60 for a mixture having an associated petroleum gas composition), while also making it possible to dispense with deep cooling of the gas stream fed to a membrane module, and to carry out gas separation under insignificant cooling of the membrane on the permeate side (down to −50° C.) For more effective gas separation, permeate is collected in a liquid state. A technical effect of the invention resides in providing a method that makes it possible to efficiently remove high-boiling hydrocarbons (C3-C6) from natural gas and associated petroleum gases, as well as to obtain gas mixtures with a constant composition.
Owner:ROSNEFT OIL CO

Electronegative gas electromigration membrane separation method

The invention provides an electronegative gas electromigration membrane separation method. To-be-separated electronegative and non-electronegative mixed gas is filled into a gas separation device; electrons are generated by utilizing an electron generator in the gas separation device; after electronegative gas in the mixed gas is collided with the electrons, stable negative ions or negative ion clusters are generated; the negative ions or the negative ion clusters enter an electric field consisting of a cathode and an anode in the gas separation device together with a gas flow; a gas separation membrane is arranged in the electric field closed to the inside of the anode; the negative ions or the negative ion clusters permeate and pass through the gas separation membrane under the pushing action of electric field force and a concentration difference between two sides of the gas separation membrane; and the gas passing through the gas separation membrane is further collected, so as to implement separation of the electronegative and non-electronegative mixed gas. By adopting the method provided by the invention, system resistance of membrane gas separation can be greatly reduced; themethod is particularly applicable to the separation of electronegative gas such as O2, H2S, SO2 and the like, and non-electronegative gas such as N2, H2 and the like; and low-energy-consumption high-efficiency separation of the gas can be implemented.
Owner:WUHAN UNIV

A method for electronegative gas electromigration membrane separation

The invention provides an electronegative gas electromigration membrane separation method. To-be-separated electronegative and non-electronegative mixed gas is filled into a gas separation device; electrons are generated by utilizing an electron generator in the gas separation device; after electronegative gas in the mixed gas is collided with the electrons, stable negative ions or negative ion clusters are generated; the negative ions or the negative ion clusters enter an electric field consisting of a cathode and an anode in the gas separation device together with a gas flow; a gas separation membrane is arranged in the electric field closed to the inside of the anode; the negative ions or the negative ion clusters permeate and pass through the gas separation membrane under the pushing action of electric field force and a concentration difference between two sides of the gas separation membrane; and the gas passing through the gas separation membrane is further collected, so as to implement separation of the electronegative and non-electronegative mixed gas. By adopting the method provided by the invention, system resistance of membrane gas separation can be greatly reduced; themethod is particularly applicable to the separation of electronegative gas such as O2, H2S, SO2 and the like, and non-electronegative gas such as N2, H2 and the like; and low-energy-consumption high-efficiency separation of the gas can be implemented.
Owner:WUHAN UNIV
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