The invention relates to a self-gating material, a self-gating storage unit and a preparation method of the self-gating material, the
chemical formula of the self-gating material is GeaAsbSecTed, a, b, c and d all refer to atomic components of elements and meet 0 lt; a / (a + b + c + d) < = 0.6, 0lt; b / (a + b + c + d) < = 0.6, 0lt; c / (a + b + c + d) < = 0.6, 0lt; d / (a + b + c + d) < = 0.18. According to the GeaAsbSecTed self-gating material disclosed by the invention, the
threshold voltage is enabled to generate offset by applying pulses with different polarities, so that a storage window is formed for data storage. The GeaAsbSecTed self-gating material disclosed by the invention has good
thermal stability, relatively long erasing service life, relatively large storage window and relatively
low leakage current, a self-gating storage unit adopting the self-gating material has relatively high operation speed and relatively good cycle index, and the reliability of a device is greatly improved. Meanwhile, the self-gating preparation method is simple in process, and material components can be conveniently and accurately controlled.