The invention discloses a solar energy measuring material heat conductivity coefficient experimental device and a measuring method thereof. The solar energy measuring material heat conductivity coefficient experimental device comprises a slideway, a heating disc frame, a heat dissipating disc frame, a poor conductor sample frame, a poor conductor sample, a metal sample, a metal sample frame, a heating disc, a heat dissipating disc, a first temperature sensor, a second temperature sensor, a heat dissipation fan, a single chip computer temperature measurement and controller, a compression bolt,a compression nut and a solar photovoltaic power supply system. The measuring device is used for measuring the heat conductivity coefficient of poor conductors and metal materials by utilizing a steady state method. The device is intuitionistic in phenomenon, accurate in measurement data, small in measurement error and good in repeatability, the components are convenient to dismount and mount, thus tests can be conducted smoothly, and the problem that an existing instrument is inconvenient to dismount and mount so that the teaching progress can be slow is avoided. The device improves the testprecision and test efficiency, and can be widely applied to scientific research, education and production.