The invention relates to the field of automobile power devices, and aims to provide an expansion tank mounting structure of a hybrid electric vehicle. The expansion tank mounting structure of the hybrid electric vehicle comprises an engine expansion tank, a PEU (power electronic unit) expansion tank and a fixing bracket, wherein one side end of the PEU expansion tank is opposite to the rear part of one side end of the engine expansion tank; engaging lugs connected through connecting bolts are arranged at the front end of the PEU expansion tank and the other side end of the engine expansion tank respectively; the fixing bracket comprises a bottom plate, a vertical plate and a reinforcing plate, and the bottom plate is provided with a bottom mounting hole and connected with the lower end of the engine expansion tank and the lower end of the PEU expansion tank; the upper end of the vertical plate is connected with the rear end of the PEU expansion tank through a screw; the reinforcing plate is connected with the rear end of the engine expansion tank through a screw. According to the expansion tank mounting structure of the hybrid electric vehicle, after the engine expansion tank and the PEU expansion tank are mounted, the modal testing character, strength and spatial arrangement can meet requirements, and the fixing effect is ideal.