The invention discloses a fresh air purifier with refrigeration, heating, dehumidification and heat recovery functions. The fresh air purifier comprises a compound air processor; one end of the compound air processor is arranged in a fresh air way of the fresh air purifier, and the other end of the compound air processor is arranged in an exhaust way of the fresh air purifier; in the fresh air way, a fresh air fan is arranged on one side of the compound air processor, and a purifying module, a sterilizing module and a negative ion sterilizing module are arranged on the other side of the compound air processor in the air direction in sequence; and in the exhaust way, an exhaust fan is arranged on one side of the compound air processor, and the fresh air fan and the exhaust fan are both in signal connection with a control module. The fresh air purifier can perform such multiple air processing modes as refrigeration, heating, dehumidification, heat recovery, purification, sterilization and negative oxygen ion increment on fresh air around the clock according to environmental change.