The invention discloses a
phosphogypsum treatment device and method based on
sodium sulfate electrolysis, belonging to the technical field of
electrochemical engineering technology application. Including
electrolysis unit and reaction unit,
sulfuric acid storage tank, acid circulation pump, acid three-way valve and
sodium sulfate electrolyzer are connected sequentially, and
sulfuric acid storage tank is directly connected with
sodium sulfate electrolyzer;
sodium sulfate storage tank, alkali circulation pump, alkali three The through valve is connected to the
sodium sulfate electrolyzer in sequence, and the
sodium sulfate storage tank is directly connected to the sodium sulfate electrolyzer; the alkali three-way valve is connected to the
phosphogypsum reactor, and the
phosphogypsum reactor,
slag discharge pump, filter, filtrate storage tank and The return pump is connected in turn, and the return pump is connected with the sodium sulfate storage tank. In the treatment method of the present invention, sodium sulfate is electrolyzed to generate caustic soda and
sulfuric acid, and caustic soda reacts with phosphogypsum to generate slaked
lime. The sulfuric acid is returned to the
production line of the
phosphate fertilizer plant, and the sodium sulfate solution is recycled to recycle
calcium and
sulfur elements. The device is compact, the structure is simple, the operation is stable, the
resource recovery rate is high, there is no secondary
pollution, and zero
pollution emission is realized.