The invention provides a low-temperature co-fired ceramic material emitting white light and a preparation method thereof. The ceramic material comprises the following components in percentage by mol: 10 to 20 percent of CaO, 20 to 30 percent of B2O3, 50 to 60 percent of SiO2, and 1 to 9 percent of optical activating agent ions. The invention also relates to the preparation method of the material, namely, a sol-gel method for preparing the low-temperature co-fired ceramic material emitting white light. The invention has the advantages that: 1, the preparation process is simple and advanced, the sintering temperature is low by adopting the Sol-gel method and is between 800 DEG C and 900 DEG C, the sintering shrink rate at the temperature is controllable between 13 percent and 17 percent, and a glass ceramic material has a flat and smooth surface, as well as higher strength; 2, the dielectric constant is adjustable between 4(1MHz) and 6 (1MHz), and the coefficient of dielectric loss is lower than 0.002; 3, the light emission intensity is high, the material can emit yellow and blue light under activation of ultraviolet light with the wavelength of between 320nm and 410nm, the white light obtained by mixing the blue light and the yellow light can be used for illuminating and displaying; and 4, based on the advantages, the low-temperature co-fired ceramic material can be applied to the fields of white light LED (Light Emitting Diode) lamps, integrated ceramic substrates and other electronic devices and semiconductors, as well as microelectronic packaging materials.