The invention discloses an energy-efficient and environment-friendly vehicle comprehensive maintaining agent and a preparation method thereof. The maintaining agent comprises the following components in percentage by weight: 20 to 60 percent of polyisobutene, 1 to 5 percent of 1,1,1-trichloropropane, 1 to 3 percent of dibromoethane, 0.5 to 5 percent of organic rare earth salt, 0 to 57 percent of aviation kerosene, 0 to 4 percent of organic manganate and 0.5 to 2 percent of surfactant. In the invention, the preparation process is simple, the obtained maintaining agent can be used in both gasoline and diesel with 15 to 27 percent of fuel oil reduced and over 50 percent of tail gas reduced, and the maintaining agent also has functions of maintaining and repairing oil tanks, oil paths, oil nozzle, air valves, combustion chambers and ternary catalyst systems of vehicles, increases the power of the vehicles, makes the idle speed smooth and the acceleration flexible and powerful and greatly reduces tail gas discharge.