The invention provides a solid-state electrolyte material of a lithium ion battery. The general formula of the solid-state electrolyte material is (LimZn)MP2X12, and the solid-state electrolyte belongs to a triclinic crystal system and a P1 space group, wherein Z is a high-valence metal element, the cationic valence is more than +1 valence and less than or equal to +3 valence, and the high-valence metal element Z is at least one of Mg, Al, Ca, Ti, Cu, Zn, Ga, In, Sr, Ru, Rh, Pd, Ag, Cd, Ba, Os, Ir, Pt or Hg; M is at least one of Ge, Si, Sn, Al or P; and X is at least one of O, S or Se. The research on the micro structure characteristics of the solid-state electrolyte material (LimZn)MP2X12 indicates that the micro interaction mechanisms such as Coulomb force, Van der Waals force and the like have important effect on the structure stability of the solid electrolyte material; and by enhancing the Coulomb attraction effect among ions and enhancing the shielding of the Coulomb repulsion effect among the ions, the total energy of the material system is greatly reduced, thereby enhancing the structure stability of the solid electrolyte material.