110results about "Copper halides" patented technology

A method is disclosed for separating and recovering base metals from a used hydroprocessing catalyst originating from Group VIB and Group VIII metals and containing at least a Group VB metal. In one embodiment, the used catalyst is contacted with an ammonia leaching solution to dissolve and separate the Group VIB and VIII metals from the Group VB metal complex and coke associated with the used catalyst. The resulting Group VIB and VIII metal containing solution is processed through at least two additional precipitation and liquid / solid separation steps to produce, in separate processing streams, a Group VIB metal product solution (such as ammonium molybdate) and a Group VIII metal product solution (such as nickel sulfate). Additionally, two separate filtrate streams are generated from liquid-solid separation steps, which filtrate streams are combined and subjected to hydrolysis and oxidation (oxydrolysis) to generate a purified ammonium sulfate solution for further processing, such as for fertilizer.

A chemical process to leach copper concentrates in the presence of a concentrated solution of sulfates and chlorides. The process includes forming a high reactivity chemical paste containing a high concentration of ions in the liquid phase of the paste which react with copper ores and forms a series of soluble salts. The salts are extracted by a simple wash. Mixing equipment for handling high viscosity liquids is used. The total mixing time is about 5 minutes, after which the paste is poured into a rectangular mold, of several hundred meters per side, and is left to settle and breathe. During settling, water and sulfuric acid are added at intervals to replace that consumed by the reactions taking place during the aeration, until the reactions have virtually end. This treatment results in a dry, very resistant mass, containing the copper extracted in form of chlorine salts, and sulfate.

A process for leaching a value metal from a base metal sulfide ore, comprising the step of leaching the ore with a lixiviant comprising a chloride, an oxidant and hydrochloric acid is disclosed. The leaching is controlled, by use of low concentrations of hydrochloric acid and a redox potential, to effect formation of hydrogen sulfide from the base metal sulfide ore. The hydrogen sulfide is stripped from the leach solution, thereby reducing the amount of sulfate generated in the leach to very low levels. The leaching may also be conducted to limit the co-dissolution of platinum group metals and gold with the base value metals. The leach forms a value metal-rich leachate and a solids residue. The solids residue may be subsequently leached to recover the platinum group metals and gold. The value metal-rich leachate can be oxidized and neutralized to recover the value base metals. In an embodiment, the chloride is magnesium chloride and lixiviant solution is regenerated

An object of the present invention is to provide a method of efficiently leaching copper from a copper sulfide ore containing chalcopyrite or enargite as a main constituent under versatile conditions for actual operation.A method of leaching copper from a copper sulfide ore, characterized by comprising using, as a leaching solution, a sulfuric acid solution containing iodide ions and ferric (III) ions in an excessive amount relative to the iodide ions and leaching copper from a copper sulfide ore; or a method of leaching copper from a copper sulfide ore, characterized by comprising leaching copper from a copper sulfide ore with the use of a leaching solution further containing water-soluble ligands such as chloride ions that can stabilize ferric (III) ions in addition to the above components, is provided.

A process for leaching a value metal from a base metal sulfide ore, comprising the step of leaching the ore with a lixiviant comprising a chloride, an oxidant and hydrochloric acid is disclosed. The leaching is controlled, by use of low concentrations of hydrochloric acid and a redox potential, to effect formation of hydrogen sulfide from the base metal sulfide ore. The hydrogen sulfide is stripped from the leach solution, thereby reducing the amount of sulfate generated in the leach to very low levels. The leaching may also be conducted to limit the co-dissolution of platinum group metals and gold with the base value metals. The leach forms a value metal-rich leachate and a solids residue. The solids residue may be subsequently leached to recover the platinum group metals and gold. The value metal-rich leachate can be is oxidized and neutralized to recover the value base metals. In an embodiment, the chloride is magnesium chloride and lixiviant solution is regenerated.

A process for recovering a precious metal from a sulfidic material comprises the steps of preparing an acidic aqueous halide solution having an oxidation potential sufficient to oxidize the sulfidic material and render the precious metal soluble in the solution, adding the material to the acidic aqueous halide solution so that the sulfidic material is oxidized and the precious metal is solubilized and separating the precious metal from the oxidized sulfidic material. In addition, a process for removing a contaminant from a contaminated sulfidic material comprises the steps of mixing the material in an aqueous solution wherein a multi-valent species of a relatively high oxidation state oxidizes the contaminant to render it soluble in the solution, produces a contaminant refined material, and is reduced to a relatively lower oxidation state; and removing the contaminant from the solution while regenerating the multi-valent species to its relatively high oxidation state.

A silica nanofiber is derived from a crystalline polymer filament of a polymer including straight chain polyethyleneimine backbones, which is capable of forming a water-insoluble crystal in the presence of water molecules at room temperature, and the crystalline polymer filament in the silica concentrates metal ions, thereby realizing a composite nanofiber including metals or metal ions in the silica. Furthermore, the composite nanofiber of the present invention can be easily produced by fixing a polymer structure in the silica as the scaffold for metal ions and concentrating metal ions at the scaffold or reducing the metal ions. Furthermore, a metal-containing silica nanofiber can be easily obtained by removing a polymer component from the composite nanofiber, the composite nanofiber association, and the complex nanofiber structure. These nanofibers can be assembled and integrated, and the assembled or integrated association or structure can realize various shapes.

A method for treating a polymetallic sulfide ore containing gold and / or silver, and further containing base metals selected from the group consisting of iron, aluminum, chromium, titanium, copper, zinc, lead, nickel, cobalt, mercury, tin, and mixtures thereof, is disclosed. The method comprises the steps of grinding the polymetallic sulfide ore to produce granules, oxidizing the granules to produce oxidized granules, and chloride leaching the granules using a brine solution including dissolved halogens, as well as chloride and bromide salts.

Provided is a method for separating and recovering iodine ingredients from acid solution containing iodide ions and iron (II) ions and for efficiently producing iron (III) ions. Said method is for treating acid solution containing the iodide ions and the iron (II) ions. Said method comprises a step of oxidizing the iron (II) ions in said solution into iron (III) ions with iron-oxidizing microorganisms, the step being performed in the presence of activated carbon.