The invention is a technique for preparing cuprous chloride crystals with hydrothermal reduction, a truly original economic and environmental- protection method for producing cuprous chloride crystals, comprising the steps of: batching, dissolving, reacting, separating, post processing, etc, i.e. preparing water soluble divalent copper salt and water soluble fluoride into a mixed solution, placing still and filtering out nonsoluble impurities, using corresponding acid to regulate the [H+] concentration of the mixed solution, transferring the feed liquid into a pressure- resistant and corrosion-resistant reaction kettle, then calculating and adding in reducer, sealing and heating to not lower than 50 deg.C, making hydrothermal reaction for less than 48 h, and directly obtaining cuprous chloride crystals, cooling and filtering, then processing the obtained crystals by acid washing, water washing, alcohol washing, drying, etc, to obtain target product, where the mother filtrate can be recycled.