43results about How to "Large magnetic entropy change" patented technology

The invention belongs to the field of magnetic refrigeration materials, and discloses an Mn-Fe-P-Si magnetic refrigeration material and a preparation method thereof. The material composition is selectively Mn1.15Fe0.85P0.52Si0.45B0.03. The preparation method comprises the following steps: (1) mixing Mn sheets, Fe blocks, FeP blocks, Si blocks and B blocks after weighing according to the mass percentages of elements in a chemical formula, wherein 5% of balance is added to the Mn; (2) putting raw materials prepared in the step (1) into a vacuum electric arc furnace, and utilizing high-purity argon gas shield for smelting to obtain an alloy pig; (3) breaking up the alloy pig, putting into a vacuum rapid quenching furnace for smelting alloy, and carrying out copper mold casting; (4) sealing the copper mold casting alloy into a quartz tube, vacuumizing to below 10<-4> Pa, carrying out annealing treatment, and then rapidly quenching into cold water to obtain the magnetic refrigeration material. The mn-Fe-P-Si magnetic refrigeration material is simple in technology, low in cost, and the magnetic refrigeration material with high density and excellent magnetocaloric effect can be obtained.

The invention relates to a high-temperature high-toughness Ni-Co-Mn-Sn-Cu alloy with a high magnetocaloric effect, a preparation method, and application thereof, belongs to the technical field of magnetic materials, and particularly relates to the high-temperature high-toughness Ni-Co-Mn-Sn-Cu alloy with the high magnetocaloric effect, the preparation method, and the application thereof. The invention aims to solve the problems that an existing Ni-Mn-Sn ferromagnetic shape-memory alloy system is high in brittleness and hard to meet the use requirement under high temperature environment. A chemical general formula is Ni48-xCoxMn37Sn9Cu6, wherein x is mole fraction and is larger than 0 and smaller than or equal to 12; and the sum of mole number of elements in the alloy is 100. The method comprises the steps of (1) preparing materials; (2) carrying out electric arc meting; and (3) carrying out homogenization treatment so as to finally obtain an Ni48-xCoxMn37Sn9Cu6 magnetic refrigeration alloy material.

The invention discloses a low-temperature magnetic cooling erbium-based bulk amorphous material and belongs to the field of magnetic cooling alloys of functional materials. The low-temperature magnetic cooling erbium-based bulk amorphous material is characterized by comprising the following chemical components in percentage by atom: 55 to 65 percent of Er, 14 to 24 percent of Al and 18 to 28 percent of Co. The material can form bulk amorphous alloys under a common suction casting condition, has magnetic entropy change and magnetic cooling capability higher than those of metal Er, has a cost price lower than magnetic cooling materials such as Er-based crystalline and giant magnetic material Gd5Si2Ge2, of the same magnetic entropy change and magnetic cooling capability and is a high quality magnetic cooling material in a 2 to 50 K range.

The invention provides a rare earth-aluminum material used for magnetic refrigeration, and a preparation method and an application thereof. The material is a compound having the following general formula R3Al2, wherein R represents any one element of Gd, Tb, Dy, Ho and Er or a combination of Ho element and any one of Gd, Tb, Dy and Er. The magnetic refrigeration material has a Zr3Al2 type tetragonal crystal structure. The rare earth-aluminum material provided by the invention, particularly Ho3Al2 has an antiferromagnetic-ferromagnetic phase transition and a ferromagnetic-paramagnetic phase transition, presents a relatively large magnetic entropy change and a wide working temperature zone nearby a phase-transition temperature. The rare earth-aluminum material has a relatively large magnetic refrigeration capacity and good thermal reversibility and magnetic reversibility, and is a very ideal magnetic refrigeration material.

The invention relates to a gadolinium-based high-entropy perovskite oxide magnetic refrigeration material and a preparation method thereof, the chemical general formula of the magnetic refrigeration material is GdXO3, X is at least four elements of transition metals Cr, Mn, Fe, Co, Ni or Al, the molar content range of each component element is 10-30%, and the total content is 100%. The material has a perovskite structure, the space group is Pbnm, and the disordered arrangement of transition metal ions has typical high-entropy characteristics. The preparation method mainly comprises the following steps: dissolving rare earth salt and metal salt which are mixed according to an equal ratio in water, the molar mass ratio of ions being 1: 1; adding citric acid into the obtained salt solution, heating, preserving heat, and fully stirring the mixture to form sol; drying the sol by distillation to obtain gel; calcining the gel to obtain a sinter; and tabletting and molding the sinter, performing sintering at high temperature, and performing cooling to obtain a finished product. The gadolinium-based high-entropy perovskite oxide material prepared by the method can be applied to the field of low-temperature region magnetic refrigeration, and is low in raw material price, simple in equipment, simple and reliable in process and suitable for industrial production.

The invention discloses a fluorine bridged rare earth molecular cluster magnetic refrigeration material and a preparation method thereof. By adopting a solvothermal synthesis method, an air-stable fluorine bridged rare earth molecular cluster magnet is obtained through the reaction of a rare earth metal salt and a fluorine source. Refrigeration material, the unique weak ferromagnetic exchange makes the magnetic entropy change more difficult to saturate under low temperature and low field, and the magnetic refrigeration effect is better. The magnetic refrigeration material of fluorine bridged rare earth molecular cluster is a cluster compound, which is soluble in organic solvents, easy to process, and easy to combine with other materials or refrigeration sites, which can accurately reduce the specified temperature. The temperature in the region has a large magnetic entropy change in the low temperature region, which is an ideal material for low-temperature magnetic refrigeration materials. Due to the weak ferromagnetic exchange between rare earth ions in the cluster compound, the magnetic entropy change of the material at low temperature and low magnetic field is caused. high.

The invention relates to a europium-based low-temperature magnetic refrigeration material of a ThCr2Si2 structure and a preparation method for the europium-based low-temperature magnetic refrigeration material. The chemical general formula of the magnetic material is Eu-T-X, wherein T is Fe or Cu, and X is P or As; and the magnetic material has body-centered ThCr2Si2 tetragonal crystal structure.The method comprises the following steps of: mixing rare-earth metallic europium, transition metal and nonmetal in a ratio to form a raw material, wherein the transition metal is Fe or Cu, and the nonmetal is P or As; putting the raw material into a quartz container, vacuumizing, closing, heating the quartz container to the temperature of between 400 and 450 DEG C, preserving heat, continuously heating the quartz container to the temperature of between 800 and 900 DEG C, and preserving heat; and performing pressure molding on the product after cooling, performing high-temperature annealing and cooling, and thus obtaining a finished product. By adopting the method of slow heating and step-by-step reaction, volatilization of P or As is effectively overcome. The method is simple in process and is easily implemented, and the prepared magnetic refrigeration material has good magnetic and thermal reversible properties.

A kind of Ni-Co-Mn-Sb-Al magnetic refrigeration alloy material and preparation method thereof, the chemical general formula of described Ni-Co-Mn-Sb-Al material is Ni 46 co 4 mn 38 Sb 12‑x Al x , where 0≤x≤0.5. In the invention, the as-cast alloy ingot is prepared through raw material proportioning, repeated vacuum arc melting, and annealing treatment, thereby preparing a Ni-Co-Mn-Sb-Al magnetic refrigeration alloy block. The magnetic refrigeration material prepared by the invention has large magnetic entropy, good refrigeration effect, good mechanical properties, easy processing, simple and easy preparation method and good application prospect.

The invention discloses a method for preparing a MnFePSi-based magnetic refrigeration composite material, which belongs to the technical field of magnetic refrigeration materials. The steps include: screening MnFePSi-based magnetic refrigeration material powders with a particle size of 30-120 μm, and performing pickling pretreatment; The powder after the pickling pretreatment is suspended in a mixed solution of copper sulfate and sodium citrate at a certain concentration, and after dip-plating at room temperature for a period of time, it is taken out, cleaned and dried to obtain a core-shell MnFePSi / Cu composite powder material; The composite powder material is hot-pressed and molded under vacuum, the hot-pressing temperature is 950-1100° C., the hot-pressing pressure is 250-500 MPa, and the hot-pressing time is 1-5 minutes. The invention can obtain the MnFePSi / Cu composite magnetic refrigeration material with high thermal conductivity, high compressive strength and excellent magneto-caloric performance, which helps to promote the practical application of this type of magnetic refrigeration material.

The invention relates to a preparation method of a thin film material, and more specifically relates to a preparation method of a La0.7Ca0.25Sr0.05MnO3 ferromagnetic thin film. The preparation method comprises following steps: 1, lanthanum nitrate is added into a mixed solution of glacial acetic acid and ethylene glycol monomethyl ether so as to obtain a solution A; 2, a mixture of calcium acetate and strontium nitrate is added into the mixed solution of glacial acetic acid and ethylene glycol monomethyl ether so as to obtain a solution B; 3, manganese acetate is added into the solution B so as to obtain a solution C; 4, the solution A is mixed with the solution C, and 1 to 10ml of acetic acid is added so as to obtain a La0.7Ca0.25Sr0.05MnO3 solution; 5, a substrate is subjected to ultrasonic processing in acetone and absolute ethyl alcohol successively; 6, the La0.7Ca0.25Sr0.05MnO3 solution is added onto the processed substrate dropwise for spin coating so as to obtain a thin film D; 7, the thin film D is subjected to presintering so as to obtain a thin film E; 8, the thin film E is delivered into a rapid heat treatment furnace for roasting, and is cooled with the rapid heat treatment furnace to room temperature so as to obtain the La0.7Ca0.25Sr0.05MnO3 ferromagnetic thin film. The preparation method is capable of solving problems of existing technology used for preparing the La0.7Ca0.25Sr0.05MnO3 (LCSMO) ferromagnetic thin film that performance is poor, purity is low, density is low, and sintering temperature is too high in preparation processes. The LCSMO ferromagnetic thin film with uniform film thickness and excellent magnetocaloric effects is prepared via modified sol-gel method.

The invention discloses an amorphous composite material not containing Fe, Co, Ni, the chemical formula is (Er 0.5 Cu 0.5 ) 100‑x al x , where 10≤x≤20. The present invention also provides the preparation method of the amorphous composite material, comprising the steps of: (1) putting metal Er, Cu and Al in an electric arc furnace in proportion, melting evenly, and obtaining a master alloy ingot after cooling; (2) ) re-melting the master alloy ingot into a master alloy melt, spraying the master alloy melt onto the surface of a rotating copper roller, and quenching to obtain a strip-shaped amorphous composite material. The invention also discloses the application of the amorphous composite material as a magnetic refrigerant material. Because the amorphous composite material of the present invention does not contain elements having strong antiferromagnetic coupling effects with Er such as Fe, Co, Ni, etc., it has more excellent magneto-caloric properties, and can realize larger magneto-caloric properties with less rare earth elements. Magnetocaloric effect, while saving material cost.

The invention belongs to the field of magnetic refrigeration materials, and discloses an Mn-Fe-P-Si magnetic refrigeration material and a preparation method thereof. The material composition is selectively Mn1.15Fe0.85P0.52Si0.45B0.03. The preparation method comprises the following steps: (1) mixing Mn sheets, Fe blocks, FeP blocks, Si blocks and B blocks after weighing according to the mass percentages of elements in a chemical formula, wherein 5% of balance is added to the Mn; (2) putting raw materials prepared in the step (1) into a vacuum electric arc furnace, and utilizing high-purity argon gas shield for smelting to obtain an alloy pig; (3) breaking up the alloy pig, putting into a vacuum rapid quenching furnace for smelting alloy, and carrying out copper mold casting; (4) sealing the copper mold casting alloy into a quartz tube, vacuumizing to below 10<-4> Pa, carrying out annealing treatment, and then rapidly quenching into cold water to obtain the magnetic refrigeration material. The mn-Fe-P-Si magnetic refrigeration material is simple in technology, low in cost, and the magnetic refrigeration material with high density and excellent magnetocaloric effect can be obtained.

The invention discloses a Gd-Ni-Al-based amorphous and nanocrystalline composite material. The molecular formula of the Gd-Ni-Al-based amorphous and nanocrystalline composite material is GdaNibAlc, wherein a, b and c represent atom contents of corresponding elements, 80<=a<=90, 5.8<=b<=11.6, 4.2<=c<=8.4, and the equation that a+b+c=100 is satisfied. The Gd-Ni-Al-based amorphous and nanocrystalline composite material is of an amorphous / nanocrystalline complex phase structure and has two refrigeration temperature zones and one or two magnetic entropy change platforms, the high-temperature magnetic order temperature is 270 K or above, and the magnetic entropy change under a 5T magnetic field can reach 6.7 J / kg / K. Because magnetic transition temperature intervals are wide, the refrigeration capacity reaches up to 640 J / kg or above, and the Gd-Ni-Al-based amorphous and nanocrystalline composite material is a good magnetic refrigeration material and can be used as a magnetic refrigeration working material in the two intervals of the two refrigeration temperature zones.

The invention relates to a high-temperature high-toughness Ni-Co-Mn-Sn-Cu alloy with a high magnetocaloric effect, a preparation method, and application thereof, belongs to the technical field of magnetic materials, and particularly relates to the high-temperature high-toughness Ni-Co-Mn-Sn-Cu alloy with the high magnetocaloric effect, the preparation method, and the application thereof. The invention aims to solve the problems that an existing Ni-Mn-Sn ferromagnetic shape-memory alloy system is high in brittleness and hard to meet the use requirement under high temperature environment. A chemical general formula is Ni48-xCoxMn37Sn9Cu6, wherein x is mole fraction and is larger than 0 and smaller than or equal to 12; and the sum of mole number of elements in the alloy is 100. The method comprises the steps of (1) preparing materials; (2) carrying out electric arc meting; and (3) carrying out homogenization treatment so as to finally obtain an Ni48-xCoxMn37Sn9Cu6 magnetic refrigeration alloy material.

A big magnetic entropy variation compound and its preparing method are disclosed. It consists of NixMnyGaz (50 is less than or equal to x is less than or equal to 56, 22 is less than or equal to y is less than or equal to 30, 22 is less than or equal to z is less than or equal to 30), with martensite and magnetic conversion under -80deg.C- 80deg.C. When 53 is less than or equal to x is less than or equal to 56, 19 is less than or equal to y is less than or equal to 22, 23 is less than or equal to z is less than or equal to 26, it make austenite phase-transition temperature range and magnetic transition temperature between -20deg.C-80 deg.C by component regulation. It is prepared by proportioning nickel, mangan and gallium etc. raw materials by chemical component, laying vacuum arc furnace or inducing furnace, vacuum pumping up to 10 to the power -1 , passing argon, smelting and cooling to obtain uniform compound, homogeneous treating the compound for 24-120 hrs under 900-1100deg.C, and annealing for 12-72 hrs under 600-800deg.C. Its advantages include simple process, big magnetic entropy and regulating temperature.

The invention discloses a thulium-based metallic glass and its preparation method and application. The thulium-based metallic glass is mainly composed of thulium, and its composition is shown in formula (I), wherein, RE means selected from Ce, Pr, Nd, One or more rare earth elements in Sm, Gd, Tb, Dy, Ho and Er; T represents Co or Ni; a, b, c, d represent the atomic percentage of each element, 30≤a≤60, 5≤ b≤30, 20≤c≤25, 15≤d≤25, 50≤a+b≤60 and a+b+c+d=100. According to the thulium-based metallic glass of the present invention, the change of RE and T can modulate the amorphous forming ability on the one hand, and on the other hand can modulate the temperature range in which the magnetic transition of the thulium-based metallic glass occurs, broaden the magnetic transition region, and make it work in a wider range. It has a large magnetocaloric effect in the temperature range. TmaREbAlcTd (I).

A preparation method for manganese-ferrum-phosphorus-silicon magnetic cooling alloy belongs to the technical field of magnetic material preparation. At first, manganese powder, ferrum powder, phosphorus powder and silicon powder, which serve as raw materials, are mixed according to the mole ratio of 2-x : x : 1-y : y to obtain a nominal composition: Mn2-xFexP1-ySiy, wherein x is larger than or equal to 0.8 and less than or equal to 1.0, and y is larger than or equal to 0.4 and less than or equal to 0.6; then, the high energy ball milling is conducted and the spark plasma sintering is performed under vacuum so as to obtain a manganese-ferrum-phosphorus-silicon alloy block body; and finally, the obtained manganese-ferrum-phosphorus-silicon alloy block body is subjected to heat treatment under the protection of argon so as to obtain the manganese-ferrum-phosphorus-silicon magnetic cooling alloy with an excellent magnetocaloric property. The curie temperature of the manganese-ferrum-phosphorus-silicon magnetic cooling alloy is adjusted through regulating the manganese-ferrum ratio and the phosphorus-silicon ratio within the temperature range from 50 DEG C below zero to 50 DEG C; and the obtained manganese-ferrum-phosphorus-silicon alloy has a greater magnetic entropy change under a 2 tesla field, thereby being beneficial to be used in a room-temperature area magnetic cooling technology.