This invention discloses a high-
boron Y–Ce–Co co-substituted
nanocrystalline material and its preparation method. The general
chemical formula of the
nanocrystalline material, expressed as a percentage by
mass, is: [RE x (Y y Ce 1‑y ) 1‑x ] z Fe 100‑z‑u‑v‑w Co u M v B w The composition is defined as follows: 0 ≤ x ≤ 0.9, 0.05 ≤ y ≤ 0.9, 25 ≤ z ≤ 35, 5 ≤ u ≤ 50, 0 ≤ v ≤ 3, 1.7 ≤ w ≤ 3. This invention utilizes Y–Ce–Co co-substitution to synergistically regulate the lattice occupancy, elemental valence states, and
magnetic exchange interactions of the main phase, significantly improving the temperature stability of the Ce-rich
system. Addressing the issues of
abnormal grain growth and excessive
Laves phase precipitation caused by Co introduction, increasing the
mass percentage of B significantly enhances the
alloy's amorphous forming ability, refines the main phase grains, and suppresses the formation of harmful second phases. Based on this compositional design, a low-linear-velocity melt rapid
quenching process (12 to 18 m / s) can directly prepare materials with uniform nanocrystalline structures without subsequent
crystallization annealing, achieving high
coercivity and high
temperature resistance while significantly reducing
raw material costs.