The invention belongs to the technical field of steel preparation and particularly relates to hot stamping forming steel added with Ce alloy and a hot stamping forming technology. The hot stamping forming steel added with Ce alloy comprises the following chemical compositions in percentage by mass: 0.22-0.40% of C, 1.0-2.5% of Mn, 1.2-2.0% of Si, 0.05-0.5% of Al, 1.2-2.5% of Cr, less than 0.6% ofMo, less than 0.1% of Nb, less than 0.15% of V, 0-0.1% of Ti, 0-0.01% of B, 0.01-0.03% of P, less than 0.004% of O, less than 0.002% of S, 0.03-0.08% of Ce, less than 0.01% of Ca, less than 0.01% of Mg and the balance of Fe and unavoidable impurities. The hot stamping forming steel adopts brand new composition design and a conventional production process for production and hot stamping. Through changing the thickness and structure of oxidized scale during the heating and stamping process of hot forming steel, the problem about falling of the hot forming steel during the heating and stamping process is solved, and finally, a thin oxide layer with a stable and dense structure is formed on the surface of a stamping component, so that the problem that a die is worn because the oxide layer of the hot stamping steel falls off is solved, at the same time, shot blasting treatment is also avoided, and the hot stamping forming steel has the direct coating application condition and does not pollute the environment.